可拉伸超韧水凝胶的制备和应用

doi:10.7503/cjcu20190656

摘要/Abstract

摘要：

综述了可拉伸超韧水凝胶的设计原理及其在组织工程和柔性电子器件领域的应用. 通过将网络结构层次、化学结构、增韧机制与宏观力学性能相结合, 重点讨论了单网络水凝胶、双网络水凝胶、纳米复合水凝胶及其它水凝胶等可拉伸超韧水凝胶的研究进展, 并总结和展望了新思路和新方向.

关键词: 超韧水凝胶, 增韧机制, 单网络水凝胶, 双网络水凝胶, 纳米复合水凝胶, 组织工程, 柔性电子器件

Abstract:

In this review, we focus on the design principle of stretchable and tough hydrogels as well as the applications in the fields of tissue engineering and flexible electronic devices. Through connecting hydrogel network structures, toughening mechanisms and chemical structures with macroscopic mechanical properties, we mainly discussed the research progress of single network hydrogel, double network hydrogel, nanocomposite hydrogel and so on. The summary and outlook of the new ideas and directions of stretchable and tough hydrogels were also demonstrated at last.

Key words: Tough hydrogel, Toughness enhance, Single network hydrogel, Double network hydrogel, Nanocomposite hydrogel, Tissue engineering, Flexible electronic device

中图分类号:

TrendMD:

盛卉, 薛斌, 秦猛, 王炜, 曹毅. 可拉伸超韧水凝胶的制备和应用. 高等学校化学学报, 2020, 41(6): 1194.

SHENG Hui, XUE Bin, QIN Meng, WANG Wei, CAO Yi. Preparation and Applications of Stretchable and Tough Hydrogels ^†. Chem. J. Chinese Universities, 2020, 41(6): 1194.

图/表 10

Fig.1 Schematic of the classification and applications of stretchable and tough hydrogels (A, D) Copyright 2015, American Chemical Society; (B, C, F, G) Copyright 2018, American Chemical Society; (E) Copyright 2019, American Chemical Society.

Fig.2 Schematic of the measurement of toughness and fracture energy (A) Measurement and calculation of toughness; (B) measurement and calculation of fracture energy.

Fig.3 Schematic of different kinds of hydrogels (A) Single network hydrogel; (B) double network hydrogel; (C) nanocomposite hydrogel; (D) slide-ring hydrogel; (E) tetra-PEG hydrogel.

Table 1 Comparison of mechanical properties for various stretchable and tough hydrogels

Classification	Sample code	Young’s modulus/MPa	Break strain/ (mm·mm^-1)	Fracture strength/MPa	Toughness/ (MJ·m^-3)	Fracture energy/ (kJ·m^-2)
Single network	CB[8]-PAM^[49]	0.02—0.42	107	1.8	——	——
hydrogel	PAM-peptide-Zn^2+[50]	0.01—0.12	4.3—7.8	0.2—0.56	——	0.63—1.35
	P(NaSS-co-MPTC)^[51]	1.53	9.4	2.6	——	4
	DMAA-co-MAAc^[52]	28	ca.8	2	——	9.3
Double network	PAMPS/PAAm^[53]	0.1—10	10—20	1—10	——	0.1—4.4
hydrogel	Alginate/PAAm^[24]	0.029	23	0.156	——	8.7
	PS-DN(compression)^[54]	0.32—0.57	——	0.21—1.6	——	0.3—2.67
	Crystallized PVA/PAAm^[55]	5	ca.3.8	2.5	——	14
	Agar/PAAm^[56]	0.082	20	1	9	——
	Agar/HPAM^[57]	0.106	52.6	0.267	9.35	1
Nanocomposite	PAM/CNS^[58]	ca. 0.1	121	0.43	33.9	——
hydrogel	NPs-P-PAA^[59]	ca.0.02	26	0.11	——	5.5
	Oxidized CNT/PAACA^[60]	0.028	14.1	0.364	——	——
	Clay-PNIPA^[61]	0.1—1	10—20	>1	ca.10	——
	PDA-pGO-PAM^[62]	ca.0.01	>35	ca.0.17	——	6.78
	P(BMA-co-AA)/PAM^[63]	0.028	17.4	0.74	ca.6	——
	(PDDA/PEI)-(PSS/PAA)^[64]	0.36±0.03	24.3±1.5	1.26±0.06	19.53±0.48	——
Other hydrogel	NIPA-AAcNa-HPR-C^[65]	ca.0.01	ca.15	ca.0.033	——	——
	Carboxyl-Fe³⁺/PR^[38]	8.3	5	4	——	10
	Tetra-PEG^[36]	0.054	7.4	0.136	0.59	——
	Tetra-PEG Protein^[66]	0.027	2.5	0.035	——	——

Fig.5 Illustration of the mechanism of PAMPS/PAAm double network hydrogels (A) Chemical structure and crosslinking[53]; (B) schematic of the tensile experiments; (C) stretch mechanism[81].(A) Copyright 2009, American Chemical Society; (C) Copyright 2010, Royal Society of Chemistry.

Fig.6 Chemical structures and crosslinking of double network hydrogels based on hybrids of physical and chemical cross-linkers (A) Self-assembled peptides used in PS-DN hydrogels[54]; (B) chemical structures and crosslinking in crystallized PVA/PAAm hydrogels[55]. (A) Copyright 2016, Wiley-VCH; (B) Copyright 2014, Royal Society of Chemistry.

Fig.7 Illustration of the mechanism of nanocomposite hydrogels (A) Mechanism of the stretch of nanocomposite hydrogels; (B) 0D, 1D, 2D and 3D nanomaterials act as the cross-linker of nanocomposite hydrogels.

Fig.9 Applications of stretchable and tough hydrogels on drug release[39](A), 3D printing[41](B), wearable force sensors[44](C) and supercapacitor[43](D) (A) Copyright 2015, American Chemical Society; (B, C) Copyright 2018, American Chemical Society; (D) Copyright 2019, American Chemical Society.

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