海藻基含杂原子碳材料的制备及电化学性质

doi:10.7503/cjcu20180297

高等学校化学学报 ›› 2018, Vol. 39 ›› Issue (12): 2627.doi: 10.7503/cjcu20180297

海藻基含杂原子碳材料的制备及电化学性质

王昀¹, 贲腾²()

1. 吉林大学电子科学与工程学院
2. 化学学院, 长春 130012

收稿日期:2018-04-16 出版日期:2018-12-03 发布日期:2018-06-11
作者简介:
联系人简介: 贲腾, 男, 博士, 教授, 博士生导师, 主要从事有机多孔材料的制备与应用及手性高分子的制备与性能研究. E-mail: tben@jlu.edu.cn
基金资助:
国家自然科学基金(批准号: 21390394, 21471065, 21871103)、高等学校学科创新引智计划项目(批准号: B07016)和吉林省科技发展计划项目(批准号: 20180414009GH)资助.

Preparation and Electrochemical Performance of Seaweed-based Heteroatom-containing Carbon Materials^†

WANG Yun¹, BEN Teng^2,^*()

1. College of Electronic Science & Engineering
2. College of Chemistry, Jilin University, Changchun 130012, China

Received:2018-04-16 Online:2018-12-03 Published:2018-06-11
Contact: BEN Teng E-mail:tben@jlu.edu.cn
Supported by:
† Supported by the National Natural Science Foundation of China(Nos.21390394, 21471065, 21871103), the Program of Introducing Talents of Discipline to Universities, China(No.B07016) and the Foundation of Science and Technology Department of Jilin Province, China(No.20180414009GH).

摘要/Abstract

摘要：

以天然海藻为原料, 经条件优化制备了含杂原子的碳材料SarCW-900及LamCW-900, 对其形貌、元素成分、孔性质和石墨化程度进行分析并讨论其活化机理. 将2种材料作为电化学电容器及锂离子电池的电极材料活性物质, 分别进行电化学性能测试. 结果表明, SarCW-900及LamCW-900在被用作电化学电容器电极材料时, 比电容分别为106 F/g及85 F/g, 经5000次循环伏安稳定性测试, 比电容值稳定在101 F/g及81 F/g, 分别降低不到4%和5%, 是理想的电容器电极材料; 在被用作锂离子电池电极材料时, 经100次循环比容量分别保持在100.3及33.9 mA·h/g, 低于纯石墨的理论值, 但具有较高的稳定性.

关键词: 海洋生物, 含杂原子碳材料, 自活化, 电化学

Abstract:

Heteroatom-containing carbon materials SarCW-900 and LamCW-900 were prepared using two types of seaweeds as raw materials. The morphology, elemental composition, pore properties, graphitization degree and the activation mechanism of the carbon materials were discussed. The two carbon materials were used as electrode material in electrochemical capacitor and lithium-ion batteries, and the results of electrochemical measurements showed that the specific capacitance of SarCW-900 and LamCW-900 was 106 and 85 F/g, respectively. After 5000 voltammetry cycles, the specific capacitance was stabilized at 101 and 81 F/g, which decreased by only 4% or 5% respectively, indicating that SarCW-900 and LamCW-900 are ideal capacitor electrode materials. When they were used as lithium-ion battery electrode material, the specific capacity after 100 cycles was maintained at 100.3 and 33.9 mA·h/g for sarCW-900 and LamCW-900, respectively, lower than the theoretical value of pure graphite, but more stable.

Key words: Marine organism, Heteroatom-containing carbon material, Self-activation, Electrochemistry

中图分类号:

O613.71

TrendMD:

王昀, 贲腾. 海藻基含杂原子碳材料的制备及电化学性质. 高等学校化学学报, 2018, 39(12): 2627.

WANG Yun,BEN Teng. Preparation and Electrochemical Performance of Seaweed-based Heteroatom-containing Carbon Materials^†. Chem. J. Chinese Universities, 2018, 39(12): 2627.

图/表 7

Fig.1 TGA curves of Sar(A), Lam(B) and FTIR spectra of Sar(a) and Lam(b)(C)

Fig.2 N2 adsorption-desorption isotherms of biomasses under different carbonation conditions(A) and pore size distribution of SarCW-900(B) and LamCW-900(C)a. SarCW-900; b. Phragmites australis activated by ZnCl2; c. LamCW-900; d. SarC-900; e. SarCA-900; f. LamC-900; g. LamCA-900; h. LamCW-950; i. SarCW-950; j. directly carbonized Phragmites australis; k. LamCW-850; l. SarCW-850; m. carbonized Citrus maxima(Burm) Merr.

Fig.3 SEM(A, B, E, F), and TEM(C, D, G, H) images and EDS(I, J) of Sar(A, B, C, D, I) and Lam(E, F, G, H, J) before and after pyrolysis(A, I) Sar; (B—D) SarCW-900; (E, J) Lam; (F—H) LamCW-900.

Fig.4 XRD patterns(A) and Raman spectra(B) of SarCW-900(a) and LamCW-900(b)

Fig.5 XPS spectra of SarCW-900(A) and LamCW-900(B)

Fig.6 Electrochemical measurement of SarCW-900(A—C), LamCW-900(E—G) and long-term cycle stability of SarCW-900(D) and LamCW-900(H) at scan rate of 0.1 V/s(A, E) Cyclic voltammetry curves at scan rate of 0.1, 0.05, 0.02, 0.01, 0.005, 0. 001 V/s; (B, F) galvano-static charge-discharge curves at current density of 1, 2, 5, 10, 20 A/g; (C, G) nyquist plots.

Fig.7 Charge/discharge behavior of SarCW-900(A—D) and LamCW-900(E—H)(A, E) Voltage profiles in the first cycle between 0.01 and 3.0 V at a current density of 0.1 C; (B, F) Voltage profiles in the 20th, 50th, 80th and 100th cycle at a current density of 0.1 C; (C, G) Cycling performance at a current density of 0.1 C for 100 cycles; (D, H) CV curves at a scaning rate of 0.2 mV/s for 5 cycles.

参考文献 28

[1]	Elliott D.C., Hart T.R., Schmidt A.J., Neuenschwander G.G., Rotness L.J., Olarte M.V., Zacher A.H., Albrecht K.O., Hallen R.T., Holladay J.E., Algal Res.,2013, 2(4), 445—454
[2]	Ghazali S.M., Salleh H., Dagang A.N., Ghazali M. S.M., Khamsan M. E.A., Ahmad Z., Ali N. A.N., AIP Conference Proceedings,2017, 1824, 030022
[3]	Gupta R., Vadodariya N., Mahto A., Chaudhary J.P., Parmar D.B., Srivastava D.N., Nataraj S.K., Meena R.J., Appl. Electrochem.,2018, 48(1), 37—48
[4]	Piñero E.R., Cadek M., Wachtler M., Béguin F., Chemsuschem., 2011, 4(7), 943—949
[5]	Wang D.F., Zhang F.F., Tang J., Electrochemistry,2015, 83(2), 84—90
[6]	Wang Y.Q., Zhang Z.Q., Zhu S.Y., Sun D.Y., Jin Y.C.J., Appl.Electrochem., 2017, 47(5), 631—639
[7]	Paskaleva E.E., Lin X.D., Duus K., McSharry J.J., Veille J. C.L., Thornber C., Liu Y.Z., Lee D. Y.W., Canki M., J. Virol.,2008, 5(1), 8
[8]	Piñero E.R., Cadek M., Béguin F., Adv. Funct. Mater.,2009, 19, 1032—1039
[9]	Zerban F.W., Freeland E.C., J. Ind. Eng. Chem.,1918, 10(10), 812—814
[10]	Peng W.M., Wu Q.Y., Tu P.G., J. Appl. Phycol.,2001, 13(1), 5—12
[11]	Barbieri O., Hahn M., Herzog A., Kötz R., Carbon,2005, 43(6), 1303—1310
[12]	Wang K.L., Cao Y.H., Gu Z.R., Ahrenkiel P., Lee J., Fan Q.H., RSC Adv.,2016, 6(32), 26738—26744
[13]	Zheng F.C., Liu D., Xia G.L., Yang Y., Liu T., Wu M.Z., Chen Q.W., J. Alloy. Compd.,2017, 693, 1197—1204
[14]	Li Y.M., Xu S.Y., Wu X.Y., Yu J.Z., Wang Y.S., Hu Y.S., Li H., Chen L.Q., Huang X.J., J. Mater. Chem. A,2014, 3(1), 71—77
[15]	Shen T., Xie D., Tang W.J., Wang D.H., Zhang X.Q., Xia X.H., Wang X.L., Tu J.P., Mater. Res. Bull.,2017, 96(4), 340—346
[16]	Ma X.L., Ning G.Q., Qi C.L., Xu C.G., Gao J.S., ACS Appl. Mater. Inter.,2014, 6(16), 14415—14422
[17]	Kleinsorge B., Feranri A.C., Robertson J., Milne W.I., J. Appl. Phys.,2000, 88(2), 1149—1157
[18]	Wang H.L., Gao Q.M., Hu J., Chen Z., Carbon,2009, 47(9), 2259—2268
[19]	Liu Z.W., Peng F., Wang H.J., Yu H., Zheng W.X., Yang J., Angew. Chem. Int. Edit.,2011, 50(14), 3257—3261
[20]	Fahmi R., Bridgwater A.V., Donnison I., Yates N., Jones J.M., Fuel,2008, 87(7), 1230—1240
[21]	Vassilev S.V., Baxter D., Andersen L.K., Vassileva C.G., Morgan T.J., Fuel,2012, 94(1), 1—33
[22]	Loffler G.L., Warcadalam V.J., Winter F., Fuel,2002, 81(6), 711—717
[23]	Huang Y., Yin X., Wu C., Wang C., Xie J., Zhou Z., Ma L., Li H., Biotechnol. Adv.,2009, 27(5), 568—572
[24]	Nielsen H.P., Baxter L.L., Sclippab G., Morey C., Frandsen F.J., Johansen K.D., Fuel,2000, 79(2), 131—139
[25]	Hamon Y., Brousse T., Jousse F., Topart P., Buvat P., Schleich D.M., J. Power Sources,2001, 97/98(7), 185—187
[26]	Park C.M., Kim Y.U., Kim H., Sohn H.J., J. Power Sources,2006, 158(2), 1451—1455
[27]	Aranguren P.L., Berti N., Dao A.H., Zhang J.X., Cuevas F., Latroche M., Jordy C., J. Power Sources,2017, 357, 56—60
[28]	Fan Z., Yan J., Ning G., Wei T., Zhi L., Wei F., Carbon,2013, 60(14), 558—561

海藻基含杂原子碳材料的制备及电化学性质

Preparation and Electrochemical Performance of Seaweed-based Heteroatom-containing Carbon Materials^†

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 28

相关文章 15

编辑推荐

Metrics

本文评价

[1]	范建玲, 唐灏, 秦凤娟, 许文静, 谷鸿飞, 裴加景, 陈文星. 氮掺杂超薄碳纳米片复合铂钌单原子合金催化剂的电化学析氢性能[J]. 高等学校化学学报, 2022, 43(9): 20220366.
[2]	江博文, 陈敬轩, 成永华, 桑微, 寇宗魁. 单原子材料在电化学生物传感中的研究进展[J]. 高等学校化学学报, 2022, 43(9): 20220334.
[3]	王瑞娜, 孙瑞粉, 钟添华, 池毓务. 大尺寸石墨烯量子点组装体的制备及电化学发光性能[J]. 高等学校化学学报, 2022, 43(8): 20220161.
[4]	李玉龙, 谢发婷, 管燕, 刘嘉丽, 张贵群, 姚超, 杨通, 杨云慧, 胡蓉. 基于银离子与DNA相互作用的比率型电化学传感器用于银离子的检测[J]. 高等学校化学学报, 2022, 43(8): 20220202.
[5]	王丽君, 李欣, 洪崧, 詹新雨, 王迪, 郝磊端, 孙振宇. 调节氧化镉-炭黑界面高效电催化CO₂还原生成CO[J]. 高等学校化学学报, 2022, 43(7): 20220317.
[6]	龚妍熹, 王建兵, 柴歩瑜, 韩元春, 马云飞, 贾超敏. 钾掺杂g-C₃N₄薄膜光阳极的制备及光电催化氧化降解水中双氯芬酸钠性能[J]. 高等学校化学学报, 2022, 43(6): 20220005.
[7]	李祎頔, 田晓春, 李俊鹏, 陈立香, 赵峰. 半导体-微生物界面电子传递及其在环境领域的应用[J]. 高等学校化学学报, 2022, 43(6): 20220089.
[8]	樊小勇, 朱永强, 毋妍, 张帅, 许磊, 苟蕾, 李东林. 三维多孔Sn-Zn合金电极助力Zn的均匀沉积/剥离[J]. 高等学校化学学报, 2022, 43(4): 20210861.
[9]	刘家琪, 李天保. BiVO₄/CuBi₂O₄薄膜光电极的制备及光电性能[J]. 高等学校化学学报, 2022, 43(4): 20220017.
[10]	侯从聪, 王惠颖, 李婷婷, 张志明, 常春蕊, 安立宝. N-CNTs/NiCo-LDH复合材料的制备及电化学性能[J]. 高等学校化学学报, 2022, 43(10): 20220351.
[11]	马鉴新, 刘晓东, 徐娜, 刘国成, 王秀丽. 一种具有发光传感、安培传感和染料吸附性能的多功能Zn(II)配位聚合物[J]. 高等学校化学学报, 2022, 43(1): 20210585.
[12]	魏闯宇, 陈艳丽, 姜建壮. 基于乙硫基取代的三层酞菁铕二聚体修饰ITO电极构筑电化学多巴胺和尿酸传感器[J]. 高等学校化学学报, 2022, 43(1): 20210582.
[13]	蒋君, 宫田田, 张成鹏, 刘晓倩, 赵俊伟. 吡啶二羧酸修饰的稀土嵌入碲钨酸盐的合成及电化学生物识别性质[J]. 高等学校化学学报, 2022, 43(1): 20210561.
[14]	鲍俊全, 郑仕兵, 苑旭明, 史金强, 孙田将, 梁静. 有机盐PTO(KPD)₂作为高性能锂离子电池正极材料的研究[J]. 高等学校化学学报, 2021, 42(9): 2911.
[15]	唐定, 衷水平. Bi_1-_xFe_xVO₄薄膜光阳极的制备及光电化学性能[J]. 高等学校化学学报, 2021, 42(8): 2509.

海藻基含杂原子碳材料的制备及电化学性质

Preparation and Electrochemical Performance of Seaweed-based Heteroatom-containing Carbon Materials†

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 28

相关文章 15

编辑推荐

Metrics

本文评价

Preparation and Electrochemical Performance of Seaweed-based Heteroatom-containing Carbon Materials^†