谷胱甘肽修饰金纳米棒的制备及与Cu2+的作用

doi:10.7503/cjcu20160406

高等学校化学学报 ›› 2016, Vol. 37 ›› Issue (7): 1239.doi: 10.7503/cjcu20160406

• 研究论文: 无机化学 • 上一篇下一篇

谷胱甘肽修饰金纳米棒的制备及与Cu²⁺的作用

张龄月², 迟娅楠¹, 单桂晔¹(), 陈艳伟¹, 刘娜²

1. 东北师范大学物理学院, 长春 130024
2. 吉林大学环境与资源学院, 长春 130012

收稿日期:2016-06-06 出版日期:2016-07-10 发布日期:2016-06-20
基金资助:
国家自然科学基金(批准号: 11174047, 11374046)资助

Preparation of GSH-Modified Au Nanorods and Their Interaction with Copper Ions^†

ZHANG Lingyue², CHI Yanan¹, SHAN Guiye^1,^*(), CHEN Yanwei¹, LIU Na²

1. School of Physics, Northeast Normal University, Changchun 130024, China
2. College of Environment and Resources, Jilin University, Changchun 130012, China

Received:2016-06-06 Online:2016-07-10 Published:2016-06-20
Contact: SHAN Guiye E-mail:shangy229@nenu.edu.cn
Supported by:
† Supported by the National Natural Science Foundation of China(Nos.11174047, 11374046)

摘要/Abstract

摘要：

制备了谷胱甘肽(GSH)功能化的金纳米棒复合材料, 根据金纳米棒的等离子体吸收峰对其组装排列敏感的特性, 研究了功能化的金纳米棒在不同pH值下的组装行为及与Cu²⁺离子作用后引起的聚集程度、排列方式和光学吸收等变化. 同时, 测试了纯金纳米棒和谷胱甘肽修饰的金纳米棒分别与铜离子作用后所得复合材料的光热转换性能. 结果表明, 相对于纯金纳米棒材料强的光热转换效应, 铜离子能明显降低复合材料的光热转换效应, 与其它金属离子比较, GSH修饰的金纳米棒的等离子光学特性对铜离子具有选择性的变化.

关键词: 金纳米棒, 谷胱甘肽, 铜离子, 等离子体共振吸收, 无机纳米复合材料

Abstract:

Au nanorods(Au NRs) modified by glutathione(GSH) were prepared. Based on the dependence of localized surface plasmon resonance(LSPR) peak shift on their arrangement, the structure and optical properties of GSH-modified Au NRs was studied at different pH conditions. At pH=5, some metal ions were chosen to detect the effect of their interaction with GSH-Au NRs on the LSPR peak of Au NRs. The results demonstrate that Cu²⁺ can obviously induce red shift of LSPR peak comparing with other metal ions. The reason is the rearrangement of Au NRs induced by Cu²⁺. Meanwhile, the photothermal experiment for pure Au NRs and GSH-Au NRs with copper ions were carried out to detect the effect of copper ions on optical properties of Au NRs. Comparing with pure Au NRs, GSH-Au NRs with copper ions decreased the efficiency of phothothermal conversion. During photothermalcoversion process, copper maybe capture the electron of Au NRs and decrease the efficiency of nonirradiation. So, Au NRs modified by GSH show the selective detection for Cu²⁺. The results here maybe provide a new method for detection of heavy metal ions.

Key words: Au Nanorods, Glutathione(GSH), Cu2+ ion, Localized surface plasmon resonance(LSPR) absorption, Inorganic nanocomposite

TrendMD:

张龄月, 迟娅楠, 单桂晔, 陈艳伟, 刘娜. 谷胱甘肽修饰金纳米棒的制备及与Cu²⁺的作用. 高等学校化学学报, 2016, 37(7): 1239.

ZHANG Lingyue, CHI Yanan, SHAN Guiye, CHEN Yanwei, LIU Na. Preparation of GSH-Modified Au Nanorods and Their Interaction with Copper Ions^†. Chem. J. Chinese Universities, 2016, 37(7): 1239.

图/表 7

Fig.1 LSPR spectra of pure Au nanorods(a) and Au nanorods modified with GSH molecular at different pH valuespH: b. 2; c. 3; d. 4; e. 5; f. 6; g. 11; h. 12.

Fig.2 TEM images of pure Au nanorods(A), GSH-Au NRs at pH=2(B) and pH=12(C)

Fig.3 Surface zeta potential of GSH-Au NRs at different pH values

Fig.4 Absorption spectra of GSH-Au NRs with Cu2+ of different concentrationsc(Cu2+)/(mmol·L-1): a. 0; b. 0.080; c. 0.205; d.0.425.

Fig.5 TEM image of GSH-Au NRs with 0.205 mmol/L Cu2+ at pH=5

Fig.6 Effects of different metal ions on LSPR absorption of GSH-Au NRsa. Au NRs; b. Ca2+; c. Zn2+; d. Mg2+; e. Mn2+; f. Na+; g. Fe3+; h. Al3+; i. Cu2+.

Fig.7 Photothermal curves before and after irradiation(A) and the infrared images of Au NRs(B), GSH-Au NRs+0.01 mmol/L Cu2+(C) and GSH-Au NRs+1 mmol/L Cu2+(D) under laser irradiation

参考文献 26

[1]	Zhang W., Zhang H., Williams S. E., Zhou A., Talanta,2015, 132, 321—326
[2]	Tsekenisa G., Filippidoub M. K., Chatzipetrouc M., Tsoutib V., Zergiotic I., Chatzandroulis S., Sensors and Actuators B,2015, 208, 628—635
[3]	Schneider E., Clark D. S., Biosens. Bioelectron., 2013, 39, 1—13
[4]	Turnlund J. R., Am. J. Clin. Nutr., 1998, 67, 960—964
[5]	Yuan C., Zhang K., Zhang Z., Wang S., Anal. Chem., 2012, 84, 9792—9801
[6]	Fu X., Lou T., Chen Z., Lin M., Feng W., Chen L., ACS Appl. Mater. Interfaces,2012, 4, 1080—1086
[7]	Wang Y., DePrince A. E., Gray S. K., Lin X. M., Pelton M., J. Phys. Chem. Lett., 2012, 1, 2692—2698
[8]	Nie Z., Fava D., Kumacheva E., Zou S., Walker G. C., Rubinstein M., Nat. Mater., 2007, 6, 609—614
[9]	Thomas K. G., Barazzouk S., Ipe B. I., Joseph S. T. S., Kamat P. V., J. Phys. Chem. B,2004, 108, 13066—13068
[10]	Varghese N., Vivekchand S. R. C., Govindaraj A., Rao C. N. R., Chem. Phys. Lett., 2008, 450, 340—344
[11]	Moussawi R. N., Patra D., J. Phys. Chem. C,2015, 119, 19458—19468
[12]	Lu L.L., Xia Y. S., Anal. Chem., 2015, 87, 8584—8591
[13]	Wang J., Dong B., Chen B., Xu S., Zhang S., Yu W., Xu C.X., Song H.W., Dalton Trans., 2013, 42, 11548—11558
[14]	Thomas K. G., Barazzouk S., Ipe B. I., Joseph S. T. S., Kamat P. V., J. Phys. Chem. B,2004, 108, 13066—13068
[15]	Varghese N., Vivekchand S. R. C., Govindaraj A., Rao C. N. R., J. Chem. Phys. Lett., 2008, 450, 340—344
[16]	Joseph S. S. T., Ipe B. I., Pramod P., Thomas K. G., J. Phys. Chem. B,2005, 110, 150—157
[17]	Nakashima H., Furukawa K., Kashimura Y., Torimitsu K.,Chem. Commun., 2007, 1080—1082
[18]	Deng J. J., Yu P., Wang Y. X., Yang L. F., Mao L. Q., Adv. Mater., 2014, 26, 6933—6943
[19]	Sudeep P. K., Joseph S. T. S., Thomas K. G. S., J. Am. Chem. Soc., 2005, 127, 6516—6517
[20]	Zhang Z.Y., Chen Z. P., Qu C. L., Chen L. X., Langmuir,2014, 30, 3625—3630
[21]	Chai F., Wang C. G., Wang T. T., Li L., Su Z. M., ACS Nano,2010, 2, 1466—1470
[22]	Niidome T., Akiyama Y., Shimoda K., Kawano T., Mori T., Katayama Y., Niidome Y., Small,2008, 4, 1001—1007
[23]	Kou X. S., Zhang S. Z., Yang Z., T sung C. K., Stucky G. D., Sun L. D., Wang J. F., Yan C. H., J. Am. Chem. Soc., 2007, 129, 6402—6404
[24]	Xiao M. D., Chen H. J., Ming T., Shao L., Wang J. F., J. Am. Chem. Soc., 2010, 11, 6565—6572
[25]	Muhammed M. A. H., Döblinger M., Rodríguez-Fernández J., J. Am. Chem. Soc., 2015, 137, 11666—11677
[26]	Staveren H. J. V., Moes C. J. M., Marie J. V., Prahl S. A., Gemert M. J. C., Appl. Opt., 1991, 30, 4507—4514

谷胱甘肽修饰金纳米棒的制备及与Cu²⁺的作用

Preparation of GSH-Modified Au Nanorods and Their Interaction with Copper Ions^†

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