高等学校化学学报

高等学校化学学报 ›› 2013, Vol. 34 ›› Issue (1): 108.doi: 10.7503/cjcu20120375

• 有机化学 • 上一篇    下一篇

Schiff碱式双功能离子液体的制备与表征

高丽霞, 余江   

  1. 北京化工大学化学工程学院, 环境催化与分离过程研究组, 北京 100029
  • 收稿日期:2012-04-18 发布日期:2012-12-31
  • 通讯作者: 余江,男,博士,教授,博士生导师,主要从事环境催化与分离技术研究.E-mail:jyu0017@yahoo.com.cn E-mail:jyu0017@yahoo.com.cn
  • 基金资助:

    国家自然科学基金(批准号: 21206007); 中国博士后科学基金项目(批准号: 2011M500224)和中央高校基本科研业务费专项资金(批准号: ZY1130)资助.

Synthesis and Characterization of Task-specific Schiff-base Ionic Liquid

GAO Li-Xia, YU Jiang   

  1. Research Group of Environmental Catalysis & Separation Process, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2012-04-18 Published:2012-12-31
  • Contact: O627.8 E-mail:jyu0017@yahoo.com.cn

PDF (PC)

被引次数

5

摘要：

分步合成法了Schiff碱式双反应中心的功能化离子液体: 首先通过1-丙胺基-3-甲基咪唑氯与FeCl3合成含有-NH2的Fe基离子液体; 然后通过1,3-二氨基-2-丙醇与3,5-二叔丁基水杨醛合成Schiff碱配体H2L及其Co配合物CoL, 再通过4-氯丁酰氯的酰氯基与配合物CoL的-OH反应生成含有-CH2Cl的配合物CH2Cl-CoL; 最后通过Fe基离子液体的-NH2与配合物CH2Cl-CoL的-CH2Cl之间的键合反应合成Schiff碱式双功能离子液体. 通过有机元素分析、 红外光谱、 紫外-可见光谱、 核磁共振波谱、 电喷雾电离质谱、 电感耦合等离子体-质谱和拉曼光谱对各化合物进行了结构表征, 确定Schiff碱式双功能离子液体的阳离子为Schiff碱Co络合阳离子, 阴离子为Fe的络合阴离子.

关键词: Schiff碱, 铁, 功能化离子液体

Abstract:

Task-specific Schiff-base ionic liquid with double reactivity centers was prepared by step synthesis. Firstly, Fe-based ionic liquid with the functional group of -NH2 was synthesized by the reaction of 1-propylamine-3-methylimdazolium chloride and FeCl3. Secondly, Schiff-base ligand H2L was prepared by the reaction of 1,3-diamino-2-hydroxypropane and 3,5-di-tert-butylsalicylaldehyde, and its cobalt complex CoL was also prepared. Complex CH2Cl-CoL with the functional group of -CH2Cl was synthesized by the reaction of 4-chlorobutyryl chloride and complex CoL. Finally, task-specific Schiff-base ionic liquid was prepared by the reaction between -NH2 and -CH2Cl of the above two compounds. The compounds synthesized were characterized by elemental analysis, infrared spectrometry(IR), UV-Visible spectroscopy(UV-Vis), 1H nuclear magnetic resonance spectra(1H NMR), Mass spectrometry(MS), inductively coupled plasma mass spectro-metry(ICP-MS) and Raman spectrometry. Task-specific Schiff-base ionic liquid was confirmed to be prepared successfully and to be composed by Schiff-base Co complex cation and Fe complex anion.

Key words: Schiff-base, Fe, Task-specific ionic liquid

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