Catalytic Oxidation of α-Eicosanol to α-Eicosanoic Acid over MCM-48 Molecular Sieves Containing Transition Metal

Abstract

Abstract: A series of MCM48 mesoporous molecular sieves containing copper, zirconium, chromium, cobalt, manganese, molybdenum and iron were prepared by hydrothermal crystallization and characterized by IR, Py IR and XRD. The series of molecular sieves were used to perform the catalytic oxidation of α-long chain eicosanol to the corresponding α-eicosanoic acid. The results monitored by IRtechnique were consistent with those of chemical analysis.

Key words: M-MCM-48-catalyst, α-Eicosanol, α-Eicosanoic acid, Catalytic oxidation

CLC Number:

O643.1

TrendMD:

WEI Chang-Ping, CAI Qiang, WANG Hai-Jun, BI Ying-Li, PANG Wen-Qin, ZHEN Kai-Ji . Catalytic Oxidation of α-Eicosanol to α-Eicosanoic Acid over MCM-48 Molecular Sieves Containing Transition Metal[J]. Chem. J. Chinese Universities, 1998, 19(7): 1154.

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Catalytic Oxidation of α-Eicosanol to α-Eicosanoic Acid over MCM-48 Molecular Sieves Containing Transition Metal

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