New 1D Ladder-Like Chain Polyoxometalate Consisting of the Paradodecatungstate Linked by Mn2+ Ions

Chem. J. Chinese Universities

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New 1D Ladder-Like Chain Polyoxometalate Consisting of the Paradodecatungstate Linked by Mn²⁺ Ions

GAN Xiong^1,2, ZHANG Zhi-Ming¹, WANG En-Bo¹*

1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, China;
2. Department of the Biology and Chemistry, Qinzhou College, Qinzhou 535000, China

Received:2007-04-28 Revised:1900-01-01 Online:2007-12-10 Published:2007-12-10
Contact: WANG En-Bo

Abstract

Abstract: A new 1D ladder-like chain polyoxotungstate K₆[Mn₂(H₂O)₈(H₂W₁₂O₄₂)]·14.5H₂O(1) was synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, TG analysis, UV, CV and single crystal X-ray diffraction. The interesting characteristics of compound 1 show that the paradodecatungstate [H₂W₁₂O₄₂]^10- anions are linked by Mn²⁺ ions forming a ladder-like one-dimensional chainlike structure, which is connected by K⁺ ions a 3D framework. The oxidation states of W and Mn sites in this compound are determined to be +6 and +2, respectively.

Key words: Polyoxometalates, Crystal structure, Manganese, Paradodecatungstate

CLC Number:

O614

TrendMD:

GAN Xiong^1,2, ZHANG Zhi-Ming¹, WANG En-Bo¹*. New 1D Ladder-Like Chain Polyoxometalate Consisting of the Paradodecatungstate Linked by Mn²⁺ Ions[J]. Chem. J. Chinese Universities, doi: .

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New 1D Ladder-Like Chain Polyoxometalate Consisting of the Paradodecatungstate Linked by Mn²⁺ Ions

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