Proton Conduction Property of a Manganese Phosphite Open Framework Compound†

doi:10.7503/cjcu20170645

Abstract

Abstract:

An open-framework manganese(Ⅱ) phosphite, ??NH₄??₄[Mn₄(PO₃H)₆](JIS-10), was synthesised via ionothermal method using 1-pentyl-3-methylimidazolium bromide([Pemim]Br) as the solvent and the proton conduction property of the crystal was studied. The proton conductivity of the as-synthesized JIS-10 is increased from 5.32×10^-4 S/cm(7 d) to 1.065×10^-3 S/cm(60 d) at 98% relative humidity, the saturation degree of absorbed water plays an important role in the enhancement of conductivity. While in an anhydrous atmosphere, JIS-10 hardly conducts electricity.

Key words: Ionothermal synthesis, Manganese phosphite open framework compound, Proton conduction

CLC Number:

O614

TrendMD:

WANG Zhixiu, MU Ying, WANG Yilin, SUN Xiaoyuan, SU Tan, LIU Jingyao. Proton Conduction Property of a Manganese Phosphite Open Framework Compound^†[J]. Chem. J. Chinese Universities, 2018, 39(6): 1138.

Figures/Tables 6

Fig.1 [Mn2O9] dimer diagrammatic sketch(A), [Mn2O9] dimer unit from crystal structure of JIS-10(B) and crystal structure of JIS-10 viewed along the [100] direction(C)

Fig.2 AC impedance plots of JIS-10b(A), JIS-10c(B) and JIS-10d(C) at room temperature under 98% RH

Fig.3 AC impedance plots of JIS-10c(A) and JIS-10d(B) and Arrhenius type plots of JIS-10c(C) and JIS-10d(D) at different temperatures under 98% RH

Fig.4 AC impedance plots of JIS-10e at different temperatures under 67% RH

Fig.5 Arrhenius type plots of JIS-10e at different temperatures under 67% RH

Fig.6 AC impedance plots of JIS-10 at different temperatures in muffle(A) 30 ℃; (B) 40 ℃; (C) 50 ℃; (D) 60 ℃.

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