Synthesis, Structure and Electrochemical Property of Calixarene Potassium Polyoxometalates

Chem. J. Chinese Universities

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Synthesis, Structure and Electrochemical Property of Calixarene Potassium Polyoxometalates

LIU Ju-Tao^1,2*, LIU Xiao-Wei¹, FAN Sheng-Di¹, LI De-Qian²

1. Key Laboratory of Biotechnology & Bioresources Utilization the State Ethnic Affairs Commission-Ministry of Education, Dalian Nationalities University, Dalian 116600, China;
2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:2006-09-02 Revised:1900-01-01 Online:2007-07-10 Published:2007-07-10
Contact: LIU Ju-Tao

Abstract

Abstract:

One inorganic-organic hybrid and two host-guest complexes were synthesized from calix arene tetra acetic ether derivative(C₆₀H₈₀O₁₂, L) and potassium polyoxometalates. The structures of the complexes were characterized with the elemental analysis, IR, TG-DTA and X-crystallographic. X-ray crystallographic studies reveal the formation of an ionic crystal, which contains a calix-cluster and calix-cluster-calix line array, and belongs to a typical inorganic-organic hybrid(complex 1) or has a host-guest structure(complex 2 and 3) . The results of cyclic voltammograms at different scanning rates showed that the anode peak current of complex 1 was proportional to the square root of the scanning rate and the charge transfer process was controlled by pervasion. The anode peak current of complexes 2 and 3 was proportional to the scanning rate and the charge transfer process was controlled by the surface. The results suggest that there are consanguineous relationship between the anode reaction and the structure.

Key words: Potassium polyoxometalate, Calixarene derivative, Inorganic-organic hybrid, Host-guest, Crystal structure, Electrochemical property

CLC Number:

O614

TrendMD:

LIU Ju-Tao^1,2*, LIU Xiao-Wei¹, FAN Sheng-Di¹, LI De-Qian². Synthesis, Structure and Electrochemical Property of Calixarene Potassium Polyoxometalates[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Structure and Electrochemical Property of Calixarene Potassium Polyoxometalates

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