Synthesis, Crystal Structure and Photoluminescence Property of a Novel Coordination Polymer [Zn6(bta)4(2,2'-bipy)3]

Chem. J. Chinese Universities

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Synthesis, Crystal Structure and Photoluminescence Property of a Novel Coordination Polymer [Zn₆(bta)₄(2,2'-bipy)₃]

LIU Guang-Xiang¹, CHU Qian¹, KAWAGUCHI Hiroyuki², SUN Wei-Yin¹*, LIANG Hong³*

1. School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China;
2. Coordination Chemistry Laboratories, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan;
3. School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, China

Received:2006-12-19 Revised:1900-01-01 Online:2007-07-10 Published:2007-07-10
Contact: SUN Wei-Yin

Abstract

Abstract: A novel coordination polymer [Zn₆(bta)₄(2,2'-bipy)₃], with three-dimensional structure, was obtained via assembly of flexible tripodal ligand 1,3,5-benzenetriacetic acid(H₃bta) with 2,2'-bipy, Zn(NO₃)₃·6H₂O under the hydrothermal condition. The X-ray single crystal diffraction analysis reveals that the complex is monoclinic with space group Cc, a=1.7714(4) nm, b=2.4391(5) nm, c=1.7120(3) nm, β=104.39(3)°, Z=4, V=7.165(2) nm³, D_c=1.722 g/cm³, μ=2.065 mm^-1, F(000)=3768, R₁=0.0645, wR₂=0.1424 for 8019 observed reflections with goodness-of-fit 1.050. The photoluminescence property of the complex in the solid state was studied at room temperature and strong blue emission was observed.

Key words: Zn(Ⅱ), Zn(Ⅱ), Coordination polymer, Coordination polymer, Carboxylic acid ligand, Carboxylic acid ligand, Crystal structure, Crystal structure, Photoluminescence property, Photoluminescence property

CLC Number:

O614

TrendMD:

LIU Guang-Xiang¹, CHU Qian¹, KAWAGUCHI Hiroyuki², SUN Wei-Yin¹*, LIANG Hong³*. Synthesis, Crystal Structure and Photoluminescence Property of a Novel Coordination Polymer [Zn₆(bta)₄(2,2'-bipy)₃][J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Crystal Structure and Photoluminescence Property of a Novel Coordination Polymer [Zn₆(bta)₄(2,2'-bipy)₃]

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