Synthesis and Crystal Structure of Zinc Coordination Polymer with Ferrocenedicarboxylic Acid as Ligand

Abstract

Abstract: The title compound [Zn(Py)₂L]_n(L=1,2′-ferrocenedicarboxylate) was synthesized under mild conditions and its crystal structure was characterized. It crystallizes in a monoclinic system, space group C2/c with the cell parameters a=1.683 0(5) nm, b=1.380 4(3) nm, c=1.746 2(3) nm, β=108.78(2)°, V=3.840 8(15) nm³, Z=8, M_r=485.52, T=293(2) K, D_c=3.359 Mg/m³, μ= 4.073 mm^-1, F(000)=3 872, R₁=0.040 1, wR₂=0.113 2. The compound exhibits an unusual one-dimensional chain consisting of two zigzag chains.

Key words: Coordination Polymer, Ferrocenedicarboxylic Acid, Crystal structure

CLC Number:

O641

TrendMD:

LENG Si-Wei, WU Gang, XIN Ming-Hong, TANG Lu-Lu, ZHU Guang-Shan, FAN Yong, SHI Su-Hua. Synthesis and Crystal Structure of Zinc Coordination Polymer with Ferrocenedicarboxylic Acid as Ligand[J]. Chem. J. Chinese Universities, 2004, 25(5): 817.

References

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