Studies on Epoxy Resin/Montmorillonite Nanocomposites Cured with 4,4'-Diamino Diphenyl Ether Diphenyl Ketone

Chem. J. Chinese Universities

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Studies on Epoxy Resin/Montmorillonite Nanocomposites Cured with 4,4'-Diamino Diphenyl Ether Diphenyl Ketone

CUI Ji-Wen^1,2, YU Lian-Xiang¹, ZHANG Chun-Ling³, MI Xin-Yan¹, FU Tie-Zhu¹, NA Hui¹

1. College of Chemistry, Jilin University, Changchun 130021, China;
2. College of Chemistry and Pharmacy, Jiamusi University, Jiamusi 154000, China;
3. College of Materials Science and Engineering, Jilin University, Changchun 130025, China

Received:2006-03-27 Revised:1900-01-01 Online:2007-03-10 Published:2007-03-10
Contact: NA Hui

Abstract

Abstract: Ca-montmorillonite was directly modified by ion-exchang method using hexadecyl trimethyl ammonium bromide. The interlamellar spacing of the montmorillonite, corresponding to the(001) plane peak, increases from 1.49 nm for the purified MMT to 2.21 nm for the organophilic clay(C₁₆-MMT). The epoxy resin/BADK/MMT nanocomposites were prepared. The effects of content of montmorillonite and mixing conditions including mixing temperatures and mixing time on the intercalation and exfoliation behavior of epoxy/alkylammonium-montmorillonite nanocomposites after curing with curing agent(BADK) were investigated by X-ray diffraction(XRD). The X-ray patterns reveal that organoclay was intercalated by the epoxy resin during mixing process. When E51 was cured with equimolar amounts of BADK, either an intercalated or an exfoliated nanocomposites were obtained. Only under certain mixing conditions, the exfoliation nanocomposite materials could be formed.

Key words: Ca-montmorillonite, 4,4’-Diaminodiphenylether diphenyl ketone, Epoxy resin, Nanocomposite material, XRD

CLC Number:

O633.13

TrendMD:

CUI Ji-Wen^1,2, YU Lian-Xiang¹, ZHANG Chun-Ling³, MI Xin-Yan¹, FU Tie-Zhu¹, NA Hui¹. Studies on Epoxy Resin/Montmorillonite Nanocomposites Cured with 4,4'-Diamino Diphenyl Ether Diphenyl Ketone[J]. Chem. J. Chinese Universities, doi: .

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Studies on Epoxy Resin/Montmorillonite Nanocomposites Cured with 4,4'-Diamino Diphenyl Ether Diphenyl Ketone

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