Chem. J. Chinese Universities ›› 2019, Vol. 40 ›› Issue (2): 385.doi: 10.7503/cjcu20180416
• Polymer Chemistry • Previous Articles Next Articles
WANG Na1,2,*(), YANG Fei1, ZHANG Jing1, FANG Qinghong1,2
Received:
2018-06-06
Online:
2019-02-10
Published:
2018-11-15
Contact:
WANG Na
E-mail:iamwangna@syuct.edu.cn
Supported by:
CLC Number:
TrendMD:
WANG Na,YANG Fei,ZHANG Jing,FANG Qinghong. Inflame-retardant Water-borne Epoxy Resin of APP Microsphere with Carrageenan Cladding†[J]. Chem. J. Chinese Universities, 2019, 40(2): 385.
Sample | m(EP)/g | m(Curing agent)/g | m(H2O)/g | m(APP)/g | m[k-CM/ APP(2/1)]/g | m[k-CM/ APP(3/1)]/g | m[k-CM/ APP(4/1)]/g |
---|---|---|---|---|---|---|---|
EP0 | 60 | 20 | 20 | - | - | - | - |
EP1 | 45 | 15 | 20 | 20 | - | - | - |
EP2 | 45 | 15 | 20 | - | 20 | - | - |
EP3 | 45 | 15 | 20 | - | - | 20 | - |
EP4 | 45 | 15 | 20 | - | - | - | 20 |
Table 1 Formulation of steel fireproof coating*
Sample | m(EP)/g | m(Curing agent)/g | m(H2O)/g | m(APP)/g | m[k-CM/ APP(2/1)]/g | m[k-CM/ APP(3/1)]/g | m[k-CM/ APP(4/1)]/g |
---|---|---|---|---|---|---|---|
EP0 | 60 | 20 | 20 | - | - | - | - |
EP1 | 45 | 15 | 20 | 20 | - | - | - |
EP2 | 45 | 15 | 20 | - | 20 | - | - |
EP3 | 45 | 15 | 20 | - | - | 20 | - |
EP4 | 45 | 15 | 20 | - | - | - | 20 |
Sample | Mass fraction(%) | ||
---|---|---|---|
S | Ba | P | |
k-CM | 3.94 | 13.98 | 0 |
k-CM/APP(2/1) | 3.54 | 11.18 | 8.72 |
k-CM/APP(3/1) | 3.48 | 12.79 | 7.33 |
k-CM/APP(4/1) | 3.21 | 12.56 | 6.36 |
Table 2 Elemental analysis data of k-CM, k-CM/APP(2/1), k-CM/APP(3/1) and k-CM/APP(4/1)
Sample | Mass fraction(%) | ||
---|---|---|---|
S | Ba | P | |
k-CM | 3.94 | 13.98 | 0 |
k-CM/APP(2/1) | 3.54 | 11.18 | 8.72 |
k-CM/APP(3/1) | 3.48 | 12.79 | 7.33 |
k-CM/APP(4/1) | 3.21 | 12.56 | 6.36 |
Sample | Temperature(5%)/℃ | Temperature(20%)/℃ | w800(%) |
---|---|---|---|
APP | 152.3 | 282.1 | 33.5 |
k-CM/APP(2/1) | 170.1 | 218.8 | 53.7 |
k-CM/APP(3/1) | 183.9 | 232.6 | 59.5 |
k-CM/APP(4/1) | 176.7 | 228.5 | 55.7 |
Table 3 TG data of APP, k-CM/APP(2/1), k-CM/APP(3/1) and k-CM/APP(4/1)*
Sample | Temperature(5%)/℃ | Temperature(20%)/℃ | w800(%) |
---|---|---|---|
APP | 152.3 | 282.1 | 33.5 |
k-CM/APP(2/1) | 170.1 | 218.8 | 53.7 |
k-CM/APP(3/1) | 183.9 | 232.6 | 59.5 |
k-CM/APP(4/1) | 176.7 | 228.5 | 55.7 |
Sample | LOI(%) | UL-94 | Droplet | Sample | LOI(%) | UL-94 | Droplet |
---|---|---|---|---|---|---|---|
EP0 | 19.7 | No rating | Yes | EP3 | 28.5 | V-0 | No |
EP1 | 30.1 | V-0 | No | EP4 | 27.2 | V-0 | No |
EP2 | 25.9 | V-0 | No |
Table 4 LOI and UL-94 test results of different samples
Sample | LOI(%) | UL-94 | Droplet | Sample | LOI(%) | UL-94 | Droplet |
---|---|---|---|---|---|---|---|
EP0 | 19.7 | No rating | Yes | EP3 | 28.5 | V-0 | No |
EP1 | 30.1 | V-0 | No | EP4 | 27.2 | V-0 | No |
EP2 | 25.9 | V-0 | No |
[1] | Liu X.J., The Study and Preparation of the Water Bater Based Fire-retardant Coatings for Structural Steel Works, Beijing University of Chemical Technology, Beijing, 2005 |
(刘学军. 水性超薄膨胀型钢结构防火涂料的研制, 北京: 北京化工大学, 2005) | |
[2] | Rackauskaite E., El-Rimawi J., Fire Technology,2015, 51(4), 867-886 |
[3] | Kwon I. K., Kwon Y. B., International Journal of Steel Structures,2012, 12(1), 25-35 |
[4] | Yan H. W., Wei J. L., Yin B., Yang M. B., Polymer Bulletin,2015, 72(11), 2725-2737 |
[5] | Wang Z., Sui X., Jie G., Polymer Materials Science & Engineering,2012, 28(4), 39-42 |
[6] | Sun L. H., Qu Y. T., Journal of Thermal Analysis and Calorimetry,2013, 111(2), 1099-1106 |
[7] | Wu K., Song L, Wang Z, Hu Y., Polymers for Advanced Technologies,2010, 19(12), 1914-1921 |
[8] | Wang N., Xu G., Wu Y. H., Zhang J., Hu L. D., Luan H. H., Fang Q. H., Journal of Thermal Analysis and Calorimetry,2016, 123(2), 1239-1251 |
[9] | Wang N., Hu L., Zhang J., Fang Q., Journal of Thermal Analysis & Calorimetry,2016, 128(2), 1-10 |
[10] | Zi X., Zhang W Mai Y., RSC Advances,2017, 7(41), 25253-25264 |
[11] | Liang X. C., Duan J. J., Qi X., Wei X. Q., Lu A., Chemical Engineering Journal,2017, 317, 766-776 |
[12] | Wang N., Wang S., Zhang J., Fang Q. H., Fine Chemicals,2017, 34(4), 451-455, 462 |
( 王娜, 王升, 张静, 方庆红. 精细化工, 2017, 34(4), 451-455, 462) | |
[13] | Franco A., Andrés M., Betty M., Jorge P., Rodrigo T., Journal of Applied Phycology,2016, 28(2), 1275-1286 |
[14] | Liu C., Chen K., Li J. J., Acta Materiae Compositae Sinica,2015, 32(3), 728-736 |
[15] | Wang X., Hu Y., Song L., Polymer,2010, 51(11), 2435-2445 |
[16] | Zhou Y., Hao J. W., Liu G. S., Du J. X., Journal of Inorganic Chemistry,2013, 29(6), 1115-1122 |
(周友, 郝建薇, 刘国胜, 杜建新. 无机化学学报, 2013, 29(6), 1115-1122) | |
[17] | Wang X., Functionalization of Graphene and Its Epoxy Composites, and Study on Their Flame Retardant Properties and Mechanism, University of Science and Technology of China, Hefei, 2013 |
(王鑫. 石墨烯的功能化及其环氧树脂复合材料的阻燃性能及机理研究, 合肥: 中国科学技术大学, 2013) | |
[18] | Li Q., Jian H., Jiu J., Ying Y., Chem. Res. Chinese Universities,2017, 33(1), 1-7 |
[19] | Lv J. Z., Xu Y. X., Zhu D. R., Zhang L., Fine Chemicals,2001, 18(6), 341-344 |
(吕九琢, 徐亚贤, 竺栋荣, 张雳. 精细化工, 2001, 18(6), 341-344) | |
[20] | Wang K., Li D. H., Yang R. J., Polymer Materials Science and Engineering,2016, 32(7), 51-56 |
( 王珂, 李定华, 杨荣杰. 高分子材料科学与工程, 2016, 32(7), 51-56) | |
[21] | Puri R. G., Khanna A. S., Progress in Organic Coatings,2016, 92, 8-15 |
[22] | White R. H., Nam S., Parikh D. V., Fire & Materials,2013, 37(1), 46-57 |
[23] | Xie H., Lai X., Li H., China Rubber/plastics Technology & Equipment,2017, 130, 68-77 |
[24] | Wang A., Duan Y., Gu X., Zhang S., Chem. Res. Chinese Universities,2017, 33(3), 492-498 |
[25] | Wang N., Zhang Y. N., Chen J. S., Progress in Organic Coatings,2017, 109, 126-134 |
[26] | Wang N., Gao H. Y., Zhang J., Kang P., Coatings,2018, 8(5), 179-183 |
[27] | Zhang W.W., Study on Modification and Flame Retardant Mechanism of Carrageenan Fiber, Qingdao University, Qingdao, 2017 |
(张伟伟. 卡拉胶纤维的改性及阻燃机理研究, 青岛: 青岛大学, 2017) | |
[28] | Liu L. N., Qian M. B., Song P. A., ACS Sustainable Chemistry & Engineering,2016, 4(4), 2422-2431 |
[29] | Shi Y. C., Wang G. J., Journal of Coatings Technology and Research,2016, 13(3), 457-468 |
[30] | Xu M. J., Xia S. Y., Liu C. A., Li B., Chinese Journal of Polymer Science,2018, 36(5), 655-664 |
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