Synthesis and Insecticidal/Acaricidal Activities of New Pyrethroid Esters Containing Pyridine Ring

Abstract

Abstract: Preparations of new pyrethroid esters(5, 6) containing a pyridine ring in the acid moiety were described. The α and β form of α cyano 3 phenoxybenzyl esters 6 were separated chromato graphically. These compounds were screened for insecticidal activities against Mythimna separata(W.) and Aphis fabae and for miticidal activity against Tetranychus urticae. Compound 5 showed 85% mortality against Mythimna separata(W.) at 250 mg/L, and 6 β had more miticidal activity on Tetranychus urticae than fenvalerate at a mass fraction of 200 mg/L.

Key words: Pyrethroid, Pyridine, Insecticidal/acaricidal activities

CLC Number:

O626.21

TrendMD:

MA Jun An, HUANG Run Qiu. Synthesis and Insecticidal/Acaricidal Activities of New Pyrethroid Esters Containing Pyridine Ring[J]. Chem. J. Chinese Universities, 2003, 24(4): 654.

[1]	CHANG Hui, YAO Shuangquan, HAN Wenjia, KANG Xiena, ZHANG Li, LI Xinping, ZHANG Zhao. Highly Solvatochromic Terpyridine Compounds for Identification of Butanol Isomers [J]. Chem. J. Chinese Universities, 2021, 42(3): 902.
[2]	YIN Shaoyun, ZHANG Luyin, WANG Zheng, PAN Mei. Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 646.
[3]	LIN Junjie, WANG Shuang, LI Weiqiang, CUI Xin, HUANG Chao. Efficient Synthesis of Pyridine ［2，3-d］pyrimidine Derivatives by Catalyst-free Tandem Cyclization Under Microwave Irradiation [J]. Chem. J. Chinese Universities, 2020, 41(12): 2749.
[4]	WANG Lin, ZHANG Yanhui, Arzugul Muslim, LAN Haidie. Morphology and Size Regulation of Polyaniline Induced by PS-b-P2VP as Template and Its Electrochemical Characters [J]. Chem. J. Chinese Universities, 2019, 40(8): 1748.
[5]	LIU Shufeng,QIU Haiyan,JIANG Tao,ZHANG Yehua,ZHAO Yun,CHENG Hanwen,CHEN Yong. Ion Transfer Behavior of Protonated Phenazopyridine at the Liquid/Liquid Interface Modified by Functionalized Hybrid Mesoporous Silica Membrane^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 973.
[6]	ZHAO Bangtun, TAO Jingjing, CHEN Xiaoji, FU Huimin, ZHU Weimin. Synthesis, Structure and Electrochemistry of Tetrathiafulvalene Vinylogues Bearing Thienyl and Pyridyl Groups^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1449.
[7]	MIAO Ruixiang,LIU Dongqing,REN Shun,ZHU Zexian,CHEN Yingbo,ZHANG Yufeng. Foams of Supramolecular Network Constructed by Poly(calixarene-piperazine) Amide and 2,2'-Bipyridine^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2327.
[8]	WANG Xiaochuang, ZHANG Jie, XIE Jianwei. Copper/Dodecyl Substituted Hydrazide-pyridine-N-oxide Catalyzed N-Arylation of Imidazoles with Aryliodides in Water^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1178.
[9]	GAO Zhongzheng, YANG Liguo, BAI Dong, CHEN Lixia, TAO Zhu, XIAO Xin. Interaction of Inverted Cucurbit[7]uril with N,N'-dibenzyl -4,4'-pyridine Chloride^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 212.
[10]	ZHAO Bangtun, MA Shuxiu, TAO Jingjing, ZHU Weimin. Synthesis, Structures and Electrochemical Properties of Pyridine-based Tetrathiafulvalene Derivatives^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 193.
[11]	ZHAO Lun, BAI Helong, SUN Erjun, WANG Xiaofeng, WANG Zichen. Synthesis and Characterization of Novel Ni(Ⅱ) Metal-organic Frameworks with Helical Crystal Structure^† [J]. Chem. J. Chinese Universities, 2016, 37(7): 1250.
[12]	ZHANG Yan, WANG Baolei, ZHAN Yizhou, ZHANG Liyuan, LI Yonghong, LI Zhengming. Synthesis and Biological Activities of Novel 5-(Pyridine-3-yl)-1,2,4-triazole Mannich Bases and Bis-Mannich Bases Containing Piperazine Moiety^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1100.
[13]	WEN Xing, TANG Liming, LIN Wanxin. Fabrication of Environmental Responsive Copolymer One-dimensional Nanostructures Using Metallogel Fibers as Template^† [J]. Chem. J. Chinese Universities, 2015, 36(1): 180.
[14]	NIE Guizhen, LI Laisheng, CHENG Biaoping, ZHOU Rendan, ZHANG Hongfu. Enantioseparations of Dihydropyridine Drugs by Sulfobutyl Ether-β-Cyclodextrin Modified Capillary Electrochromatography^† [J]. Chem. J. Chinese Universities, 2014, 35(7): 1414.
[15]	GAO Yuanhao, PAN Ruilong, TIAN Yupeng, LI Jing, ZHENG Zhi. Syntheses and Optical Properties of Two Novel Terpyridine Derivatives^† [J]. Chem. J. Chinese Universities, 2014, 35(7): 1439.

Synthesis and Insecticidal/Acaricidal Activities of New Pyrethroid Esters Containing Pyridine Ring

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments