Nonylphenol Molecularly Imprinted 2D Photonic Crystal Hydrogel Sensor

doi:10.7503/cjcu20220757

Abstract

Abstract:

A molecularly imprinted two-dimensional photonic hydrogel sensor that can specifically recognizes nonylphenol（NP） was obtained by UV photoinitiated polymerization using polystyrene two-dimensional photonic crystal as template， NP as imprinted molecule， methanol as solvent， methacrylic acid as functional monomer， ethylene glycol dimethacrylate（EGDMA） as crosslinker， and 2，2-diethoxyacetophenone（DEAP） as initiator. The response performance of the sensor was determined by measuring the change in the diameter of the Debye diffraction ring（ΔD）. In the NP solution， the volume expansion of the hydrogel leads to the increase of the particle spacing of the photonic crystal in the gel， which leads to the decrease of the diameter of Debye diffraction ring. As the concentration of NP in the solution increases from 0 to 1×10^‒5 mo/L， the diameter of Debye diffraction ring decreases by 8.0 mm， and the particle spacing of the corresponding photonic crystal increases by 25.1 nm. In the NP concentration range of 1×10^‒13—1×10^‒8 mol/L， the change of Debye diffraction ring is linearly related to the logarithm value of NP concentration（lgc）. In addition， the detection limit of NP molecularly imprinted two-dimensional photonic crystal hydrogel sensor is as low as 1×10^‒13 mol/L， which has high sensitivity， good specificity recognition ability and stable reusability， and can realize the visual detection of nonylphenol.

Key words: Nonylphenol, Molecular imprinting technology, Two-dimensional photonic crystal, Hydrogel, Debye diffraction ring

CLC Number:

O657

TrendMD:

WANG Gang, LIU Genqi, ZHAO Lingli, WANG Yue, LIU Lisha, SUN Chenxin, MA Xiaoyan. Nonylphenol Molecularly Imprinted 2D Photonic Crystal Hydrogel Sensor[J]. Chem. J. Chinese Universities, 2023, 44(6): 20220757.

Figures/Tables 11

References 26

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Method	Linear range/（mol∙L^‒1）	Limit of detection/（mol∙L^‒1）	Ref.
Electrochemical	5×10^‒8—5×10^‒6	1×10^‒8	［4］
HPLC	4.54×10^‒7—4.54×10^‒4	4.54×10^‒7	［5］
GC⁃MS	2.27×10^‒8—4.54×10^‒6	1.14×10^‒8	［25］
HPLC⁃MS/MS	2.27×10^‒9—4.54×10^‒7	2.27×10^‒9	［26］
NP⁃MIPCH sensor	1×10^‒13—1×10^‒8	1×10^‒13	This work

Method	Linear range/（mol∙L^‒1）	Limit of detection/（mol∙L^‒1）	Ref.
Electrochemical	5×10^‒8—5×10^‒6	1×10^‒8	［4］
HPLC	4.54×10^‒7—4.54×10^‒4	4.54×10^‒7	［5］
GC⁃MS	2.27×10^‒8—4.54×10^‒6	1.14×10^‒8	［25］
HPLC⁃MS/MS	2.27×10^‒9—4.54×10^‒7	2.27×10^‒9	［26］
NP⁃MIPCH sensor	1×10^‒13—1×10^‒8	1×10^‒13	This work

Sample	Spiked concentration/（mol∙L^‒1）	Found concentration/（mol∙L^‒1）	Recovery（%）
Lake water	1×10^‒13	1.02×10^‒13	102.3
	1×10^‒11	0.93×10^‒11	93.5
	1×10^‒10	0.94×10^‒10	93.7
	1×10^‒8	0.96×10^‒8	95.7
Tap water	1×10^‒13	0.93×10^‒13	93.3
	1×10^‒11	0.91×10^-11	91.2
	1×10^‒10	1.09×10^‒10	109.6
	1×10^‒8	1.05×10^‒8	104.7

Sample	Spiked concentration/（mol∙L^‒1）	Found concentration/（mol∙L^‒1）	Recovery（%）
Lake water	1×10^‒13	1.02×10^‒13	102.3
	1×10^‒11	0.93×10^‒11	93.5
	1×10^‒10	0.94×10^‒10	93.7
	1×10^‒8	0.96×10^‒8	95.7
Tap water	1×10^‒13	0.93×10^‒13	93.3
	1×10^‒11	0.91×10^-11	91.2
	1×10^‒10	1.09×10^‒10	109.6
	1×10^‒8	1.05×10^‒8	104.7

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