Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (11): 2101.doi: 10.7503/cjcu20160363
• Polymer Chemistry • Previous Articles Next Articles
WU Xiaomeng, CHEN Xiaoyu, Shi LI, FAN Zhongyong*()
Received:
2016-05-20
Online:
2016-11-10
Published:
2016-08-31
Contact:
FAN Zhongyong
E-mail:zyfan@fudan.edu.cn
Supported by:
CLC Number:
TrendMD:
WU Xiaomeng, CHEN Xiaoyu, Shi LI, FAN Zhongyong. Preparation, Structure and Properties of PLLA-TMC/PDLA-TMC Stereocomplexes†[J]. Chem. J. Chinese Universities, 2016, 37(11): 2101.
Fig.2 1H NMR(500 MHz) spectra of sc-PLA and sc-PLA-TMC in CDCl3 a. sc-PLA; b. sc-PLA-TMC10; c. sc-PLA-TMC5; d. sc-PLA-TMC2.5. Peaks a—d are corresprnding to the positions a—d in the structure.
Sample | Feed ratio n(LLA) or n(DLA)∶n(TMC) | Compositiona n(LLA) or n(DLA)∶n(TMC) | 10-5 | 10-5 | PDI |
---|---|---|---|---|---|
PLLA | 1.1 | 1.7 | 1.5 | ||
PDLA | 1.2 | 2.0 | 1.7 | ||
PLT97.5/2.5 | 97.5∶2.5 | 97.7∶2.3 | 1.1 | 1.7 | 1.5 |
PDT97.5/2.5 | 97.5∶2.5 | 97.4∶2.6 | 1.1 | 1.7 | 1.5 |
PLT95/5 | 95∶5 | 95.7∶4.3 | 1.2 | 2.2 | 1.8 |
PDT95/5 | 95∶5 | 95.4∶4.6 | 1.2 | 2.2 | 1.8 |
PLT90/10 | 90∶10 | 90.3∶9.7 | 1.1 | 1.9 | 1.7 |
PDT90/10 | 90∶10 | 90.8∶9.2 | 1.1 | 2.0 | 1.8 |
Table 1 Molecular characterization of PL(D)LA homopolymer and PL(D)LA-TMC copolymers determined by GPC and 1H NMR
Sample | Feed ratio n(LLA) or n(DLA)∶n(TMC) | Compositiona n(LLA) or n(DLA)∶n(TMC) | 10-5 | 10-5 | PDI |
---|---|---|---|---|---|
PLLA | 1.1 | 1.7 | 1.5 | ||
PDLA | 1.2 | 2.0 | 1.7 | ||
PLT97.5/2.5 | 97.5∶2.5 | 97.7∶2.3 | 1.1 | 1.7 | 1.5 |
PDT97.5/2.5 | 97.5∶2.5 | 97.4∶2.6 | 1.1 | 1.7 | 1.5 |
PLT95/5 | 95∶5 | 95.7∶4.3 | 1.2 | 2.2 | 1.8 |
PDT95/5 | 95∶5 | 95.4∶4.6 | 1.2 | 2.2 | 1.8 |
PLT90/10 | 90∶10 | 90.3∶9.7 | 1.1 | 1.9 | 1.7 |
PDT90/10 | 90∶10 | 90.8∶9.2 | 1.1 | 2.0 | 1.8 |
Sample | Tg/℃ | Tm/ ℃ | ΔHm/(J·g-1) | fc(%) | |||
---|---|---|---|---|---|---|---|
hc crystal | sc crystal | hc crystal | sc crystal | hc crystal | sc crystal | ||
sc-PLA | 60.4 | 174.6 | 14.6 | 203.8 | 7.6 | 15.6 | 4.9 |
sc-PLA-TMC2.5 | 59.1 | 167.1 | 26.8 | 212.3 | 11.9 | 29.2 | 7.8 |
sc-PLA-TMC5 | 57.2 | 205.1 | 7.2 | 4.9 | |||
sc-PLA-TMC10 | 54.4 | 203.1 | 5.3 | 3.7 |
Table 2 Thermal properties of sc-PLA and sc-PLA-TMC
Sample | Tg/℃ | Tm/ ℃ | ΔHm/(J·g-1) | fc(%) | |||
---|---|---|---|---|---|---|---|
hc crystal | sc crystal | hc crystal | sc crystal | hc crystal | sc crystal | ||
sc-PLA | 60.4 | 174.6 | 14.6 | 203.8 | 7.6 | 15.6 | 4.9 |
sc-PLA-TMC2.5 | 59.1 | 167.1 | 26.8 | 212.3 | 11.9 | 29.2 | 7.8 |
sc-PLA-TMC5 | 57.2 | 205.1 | 7.2 | 4.9 | |||
sc-PLA-TMC10 | 54.4 | 203.1 | 5.3 | 3.7 |
Fig.6 SEM images of various solution cast films during proteinase K-catalyzed degradation (A) sc-PLA, t=0 h; (B) sc-PLA, t=120 h; (C) sc-PLA-TMC5, t=0 h; (D) sc-PLA-TMC5, t=120 h.
Sample | Eb/GPa | ||
---|---|---|---|
PLLA | 53.9 | 2.1 | 4.6 |
sc-PLA | 55.8 | 2.5 | 4.8 |
sc-PLA-TMC2.5 | 54.2 | 2.4 | 5.0 |
sc-PLA-TMC5 | 51.5 | 2.1 | 6.1 |
sc-PLA-TMC10 | 42.3 | 1.7 | 7.2 |
Table 3 Mechanical properties of sc-PLA and sc-PLA-TMC
Sample | Eb/GPa | ||
---|---|---|---|
PLLA | 53.9 | 2.1 | 4.6 |
sc-PLA | 55.8 | 2.5 | 4.8 |
sc-PLA-TMC2.5 | 54.2 | 2.4 | 5.0 |
sc-PLA-TMC5 | 51.5 | 2.1 | 6.1 |
sc-PLA-TMC10 | 42.3 | 1.7 | 7.2 |
[1] | Lunt, J. , Polym. Degrad. Stabil., 1998, 59( 1-3), 145- 152 |
[2] | Nair L., S. , Laurencin C., T. , Prog. Polym. Sci., 2007, 32( 8/9), 762- 798 |
[3] | Yanagida, H. , Okada, M. , Masuda, M. , Ueki, M. , Narama, I. , Kitao, S. , Koyama, Y. , Furuzono, T. , Takakuda, K. , J. Biosci. Bioeng., 2009, 108( 3), 235- 243 |
[4] | Li S., M. , Mccarthy, S. , Biomaterials, 1999, 20( 1), 35- 44 |
[5] | Kakuta, M. , Hirata, M. , Kimura, Y. , Polym. Rev., 2009, 49( 2), 107- 140 |
[6] | Tsuji, H. , Macromol. Biosci., 2005, 5( 7), 569- 597 |
[7] | Dobrzynski, P. , Kasperczyk, J. , J. Polym. Sci. Pol. Chem., 2006, 44( 10), 3184- 3201 |
[8] | Dong J., T. , Liao, L. , Shi, L. , Tan Z., S. , Fan Z., Y. , Li S., M. , Lu Z., Q. , Polym. Eng. Sci ., 2014, 54( 6), 1418- 1426 |
[9] | Zhang, Z. , Kuijer, R. , Bulstra S., K. , Grijpma D., W. , Feijen, J. , Biomaterials, 2006, 27( 9), 1741- 1748 |
[10] | Zhang, Z. , Grijpma D., W. , Feijen, J. , J. Mater. Sci. Mater. Med., 2004, 15( 4), 381- 385 |
[11] | Zhu K., J. , Hendren R., W. , Jensen, K. , Pitt C., G. , Macromolecules, 1991, 24( 8), 1736- 1740 |
[12] | 李伟, 马艳, 李远翔, 范仲勇. 高等学校化学学报, 2014, 35( 7), 1553- 1558 |
Li, W. , Ma, Y. , Li Y., X. , Fan Z., Y. , Chem. J. Chinese Universities, 2014, 35( 7), 1553- 1558 ( | |
[13] | Liao, L. , Dong J., T. , Wang G., X. , Fan Z., Y. , Li S., M. , Lu Z., Q. , Eur. Polym. J., 2015, 66, 429- 436 |
[14] | Tsuji, H. , Wada, T. , Sakamoto, Y. , Sugiura, Y. , Polymer, 2010, 51( 21), 4937- 4947 |
[15] | Solarski, S. , Ferreira, M. , Devaux, E. , Polymer, 2005, 46( 25), 11187- 11192 |
[16] | Sawai, D. , Tsugane, Y. , Tamada, M. , Kanamoto, T. , Sungil, M. , Hyon, S. , J. Polym. Sci. Pol. Phys., 2007, 45( 18), 2632- 2639 |
[17] | Brizzolara, D. , Cantow H., J. , Diederichs, K. , Keller, E. , Domb A., J. , Macromolecules, 1996, 29( 1), 191- 197 |
[18] | 石文鹏, 赵辰阳, 李速明, 范仲勇. 高等学校化学学报, 2012, 33(9), 2092- 2098 |
Shi W., P. , Zhao C., Y. , Li S., M. , Fan Z., Y. , Chem. J. Chinese Universities, 2012, 33( 9), 2092- 2098 ( | |
[19] | Dong J., T. , Liao, L. , Ma, Y. , Shi, L. , Wang G., X. , Fan Z., Y. , Li S., M. , Lu Z., Q. , Polym. Degrad. Stabil., 2014, 103, 26- 34 |
[1] | GAO Jing, HE Wentao, WANG Xinxin, XIANG Yushu, LONG Lijuan, QIN Shuhao. Preparation of DOPO Derivative Modified Carbon Nanotubes and Their Effect on Flame Retardancy of Polylactic Acid [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210670. |
[2] | XU Huan, KE Lyu, TANG Mengke, SHANG Han, XU Wenxuan, ZHANG Zilin, FU Yanan, HAN Guangdong, CUI Jinsheng, YANG Haoran, GAO Jiefeng, ZHANG Shenghui, HE Xinjian. In⁃situ Liquid Exfoliation of Montmorillonite Nanosheets in Poly(lactic acid) to Resist Oxygen Permeation [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220316. |
[3] | LI Yichuan, ZHU Guofu, WANG Yu, CHAI Yongming, LIU Chenguang, HE Shengbao. Effects of Substrate Surface Properties and Precursor Chemical Environment on In⁃situ Oriented Construction of Titanium Silicalite Zeolite Membranes [J]. Chem. J. Chinese Universities, 2021, 42(9): 2934. |
[4] | LI Yanyan, DUAN Linrui, LUO Jingshan. Moisture-assisted Crystallization of Inorganic Perovskite CsPbI3 Film [J]. Chem. J. Chinese Universities, 2021, 42(6): 1785. |
[5] | MIAO Weijun, WU Feng, WANG Yong, WANG Zongbao. In⁃situ Study of the Epitaxial Crystallization of PCL/RGO at High Shear Rate [J]. Chem. J. Chinese Universities, 2021, 42(3): 910. |
[6] | WANG Juan, WANG Linying, ZHU Dali, CUI Wenhao, WANG Yifeng, TIAN Peng, LIU Zhongmin. Progress in Direct Synthesis of High Silica Zeolite Y [J]. Chem. J. Chinese Universities, 2021, 42(1): 1. |
[7] | WU Qinming, WANG Yeqing, MENG Xiangju, XIAO Fengshou. Reconsideration of Crystallization Process for Aluminosilicate Zeolites [J]. Chem. J. Chinese Universities, 2021, 42(1): 21. |
[8] | XIA Yiwei, WANG Guangxin, FENG Yulin, HU Yuexin, ZHAO Guiyan. Preparation and Properties of Biobased Super-tough Poly(lactic acid) Composites [J]. Chem. J. Chinese Universities, 2020, 41(8): 1881. |
[9] | WANG Yang, WANG Sidi, TANG Shaokun. Synthesis and Characterization of Imine-based Covalent Organic Framework(COF-LZU1) in Supercritical Carbon Dioxide [J]. Chem. J. Chinese Universities, 2020, 41(8): 1792. |
[10] | HE Zhechao, XIA Kun, WANG Jing, ZHOU Dan, LU Xinhuan, XIA Qinghua. Controllable Synthesis of SAPO-5 Molecular Sieves and Exploration of the Crystallization Process [J]. Chem. J. Chinese Universities, 2020, 41(6): 1224. |
[11] | WANG Yuyao, ZHANG Qiang, YU Jihong. Synthesis of Hierarchical NaX Zeolite and Its CO2 Adsorption Performance † [J]. Chem. J. Chinese Universities, 2020, 41(4): 616. |
[12] | LUO Dongxia, LI Bing, WANG Quanyi, TIAN Peng, LIU Zhongyi, LIU Zhongmin. Study on Crystallization Process of SAPO-5 Molecular Sieve [J]. Chem. J. Chinese Universities, 2020, 41(11): 2442. |
[13] | FANG Xijie,LIU Ruiyun,LIN Sen,SHI Lei,WANG Runwei,LI Yi,LI Junying. Synthesis of STW-zeotype Germanosilicate via Steam-assisted Crystallization† [J]. Chem. J. Chinese Universities, 2019, 40(5): 867. |
[14] | ZHANG Jian,ZHU Zhaowu,LEI Ze,WANG Lina,CHEN Desheng,YI Aifei,SU Hui,QI Tao. Preparation of Vanadium Oxalate by Solvent Extraction and Purification with P507 and Its Physicochemical Properties† [J]. Chem. J. Chinese Universities, 2019, 40(4): 740. |
[15] | HAN Jiahui,HUANG Hanxiong,HUANG Yuxiao. Improving Crystallization Behavior and Melt Strength of Poly(lactic acid) via Adding Talc and PLA-g-MAH† [J]. Chem. J. Chinese Universities, 2018, 39(9): 2089. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||