Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (11): 2108.doi: 10.7503/cjcu20160282
• Polymer Chemistry • Previous Articles Next Articles
XIA Qingcheng, MAO Fei, YANG Yong, HAN Jing, LIU Xiaohui, YANG Jiazhi*(), SUN Dongping
Received:
2016-04-25
Online:
2016-11-10
Published:
2016-10-20
Contact:
YANG Jiazhi
E-mail:jiazhiyang@sina.com
Supported by:
CLC Number:
TrendMD:
XIA Qingcheng, MAO Fei, YANG Yong, HAN Jing, LIU Xiaohui, YANG Jiazhi, SUN Dongping. Properties of CeO2/PTFE/Nafion Composite Membranes Prepared by Magnetron Sputtering†[J]. Chem. J. Chinese Universities, 2016, 37(11): 2108.
Fig.2 Contact angle of CeO2/PTFE composite membrane at different sputtering time Sputtering power: 40 W. Sputtering time/s: (A) 0; (B) 30; (C) 60; (D) 90; (E) 120; (F) 150.
Fig.5 Wide range XPS spectra of PTFE membrane and CeO2/PTFE, CeO2/PTFE/Nafion composite membrane(A), narrow XPS spectra of Ce element in CeO2/PTFE composite membrane(B) and S element in CeO2/PTFE/Nafion composite membrane(C)Insets of (B) and (C) are Ce and S mapping pictures, respectively.
Fig.6 SEM images of native PTFE membrane(A), CeO2/PTFE composite membrane(B), CeO2/PTFE/Nafion composite membrane(C) and elemental analysis graph(D) of CeO2/PTFE/Nafion composite membrane
Fig.8 TGA curves of PTFE(a) and CeO2/PTFE(b—d) membranes at different sputtering time Sputtering power: 40 W. Sputtering time/s: b. 30, c. 60, d. 120.
Membrane | Length change(%) | Breadth change(%) | Thickness change(%) | Area swelling ratio(%) | Volume swelling ratio(%) |
---|---|---|---|---|---|
PTFE | 0.26 | 0.24 | 0.16 | 0.5 | 0.66 |
CeO2/PTFE | 0.27 | 0.25 | 0.18 | 0.53 | 0.71 |
CeO2/PTFE/Nafion | 0.4 | 0.38 | 0.36 | 0.75 | 1.15 |
Table 1 Swelling properties of composite membrane
Membrane | Length change(%) | Breadth change(%) | Thickness change(%) | Area swelling ratio(%) | Volume swelling ratio(%) |
---|---|---|---|---|---|
PTFE | 0.26 | 0.24 | 0.16 | 0.5 | 0.66 |
CeO2/PTFE | 0.27 | 0.25 | 0.18 | 0.53 | 0.71 |
CeO2/PTFE/Nafion | 0.4 | 0.38 | 0.36 | 0.75 | 1.15 |
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