Chem. J. Chinese Universities ›› 2014, Vol. 35 ›› Issue (10): 2156.doi: 10.7503/cjcu20140370
• Physical Chemistry • Previous Articles Next Articles
LIU Xiaoxia1, DENG Hao1, WANG Yanying1, LU Zhiwei1, ZENG Xianyin2, WANG Xianxiang1, ZOU Ping1, RAO Hanbing1,*()
Received:
2014-04-21
Online:
2014-10-10
Published:
2014-09-30
Contact:
RAO Hanbing
E-mail:rhbsau@gmail.com
Supported by:
CLC Number:
TrendMD:
LIU Xiaoxia, DENG Hao, WANG Yanying, LU Zhiwei, ZENG Xianyin, WANG Xianxiang, ZOU Ping, RAO Hanbing. Thermodynamics Studies on the BSA Adsorption onto Zinc Oxide Surfaces with Different Morphologies†[J]. Chem. J. Chinese Universities, 2014, 35(10): 2156.
Fig.6 Far-UV circular dichroism spectra(CD) of BSA in absence and in presence of ZnO a. BSA; b. BSA+ZnO NBs; c. BSA+ZnO NRs; d. BSA+ZnO NSs; e. BSA+ZnO NPs.
Fig.9 Fitting results of Langmuir adsorption models of BSA onto ZnO at 303 K(A) and 310 K(B) and Freundlich adsorption models at 303 K(C) and 310 K(D)
T/K | Material | Langmuir adsorption isotherm | Freundlich adsorption isotherm | ||||
---|---|---|---|---|---|---|---|
qmax/(μg·mg-1) | ka/(mL·μg-1) | R2 | 1/nF | KF | R2 | ||
303 | ZnO NRs | 97.0874 | 0.0109 | 0.9733 | 1.6276 | 0.3390 | 0.9698 |
ZnO NSs | 39.3701 | 0.0272 | 0.9349 | 2.1993 | 3.5059 | 0.8336 | |
ZnO NBs | 67.1741 | 0.0056 | 0.9431 | 1.3379 | 0.7571 | 0.9619 | |
ZnO NPs | 41.8410 | 0.0083 | 0.9508 | 1.4507 | 0.7819 | 0.9619 | |
310 | ZnO NRs | 94.1620 | 0.0177 | 0.9827 | 0.5147 | 5.4438 | 0.9511 |
ZnO NSs | 59.5238 | 0.0139 | 0.9545 | 0.5887 | 2.2631 | 0.9366 | |
ZnO NBs | 47.2114 | 0.0167 | 0.9852 | 0.5313 | 2.5044 | 0.9504 | |
ZnO NPs | 31.3479 | 0.0141 | 0.9528 | 0.5686 | 1.3143 | 0.9227 |
Table 1 BSA adsorption isotherm equations and parameters of Langmuir and Freundlich models of ZnO
T/K | Material | Langmuir adsorption isotherm | Freundlich adsorption isotherm | ||||
---|---|---|---|---|---|---|---|
qmax/(μg·mg-1) | ka/(mL·μg-1) | R2 | 1/nF | KF | R2 | ||
303 | ZnO NRs | 97.0874 | 0.0109 | 0.9733 | 1.6276 | 0.3390 | 0.9698 |
ZnO NSs | 39.3701 | 0.0272 | 0.9349 | 2.1993 | 3.5059 | 0.8336 | |
ZnO NBs | 67.1741 | 0.0056 | 0.9431 | 1.3379 | 0.7571 | 0.9619 | |
ZnO NPs | 41.8410 | 0.0083 | 0.9508 | 1.4507 | 0.7819 | 0.9619 | |
310 | ZnO NRs | 94.1620 | 0.0177 | 0.9827 | 0.5147 | 5.4438 | 0.9511 |
ZnO NSs | 59.5238 | 0.0139 | 0.9545 | 0.5887 | 2.2631 | 0.9366 | |
ZnO NBs | 47.2114 | 0.0167 | 0.9852 | 0.5313 | 2.5044 | 0.9504 | |
ZnO NPs | 31.3479 | 0.0141 | 0.9528 | 0.5686 | 1.3143 | 0.9227 |
Nano-material | ΔH/ (kJ·mol-1) | ΔS/ (J·mol-1·K-1) | ΔG/ (kJ·mol-1) |
---|---|---|---|
ZnO NRs | 13.41 | 95.96 | -16.34 |
ZnO NSs | 13.83 | 93.83 | -15.25 |
ZnO NBs | 12.40 | 86.84 | -14.52 |
ZnO NPs | 9.47 | 74.64 | -13.67 |
Table 2 Thermodynamic parameters of adsorption of BSA onto ZnO at 310 K
Nano-material | ΔH/ (kJ·mol-1) | ΔS/ (J·mol-1·K-1) | ΔG/ (kJ·mol-1) |
---|---|---|---|
ZnO NRs | 13.41 | 95.96 | -16.34 |
ZnO NSs | 13.83 | 93.83 | -15.25 |
ZnO NBs | 12.40 | 86.84 | -14.52 |
ZnO NPs | 9.47 | 74.64 | -13.67 |
Fig.11 Thermdynamic curves of adsorption of BSA onto ZnO a. ZnO NRs, InK0=-1612.56/T+11.54; b. ZnO NSs, InK0=-1663.89/T+11.29; c. ZnO NBs, InK0=-1491.76/T+10.44; d. ZnO NPs, InK0=-1139.50/T+8.98.
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