Proton Exchange Membrane Fuel Cells Completely Based on Pd-alloy Catalysts

doi:10.7503/cjcu20120292

Abstract

Abstract:

A series of PdCu/C catalysts were prepared using an improved impregnation method. The catalytic activities of the samples toward both the oxygen reduction reaction(ORR) and the hydrogen oxidation reaction(HOR) were characterized. Among these catalyts, Pd₉₀Cu₁₀/C exhibits the highest mass-specific catalytic activity toward the ORR, and Pd₈₀Cu₂₀/C is the best for the HOR. Single cell with Pd₉₀Cu₁₀/C as the cathode catalyst and Pd₈₀Cu₂₀/C as the anode catalyst was tested. The maximum power density of the cell is 204 mW/cm².

Key words: PdCu alloy, Oxygen reduction reaction, Hydrogen oxidation reaction, Proton exchange membrane fuel cell

CLC Number:

O646

TrendMD:

HU Qing-Ping, PAN Jing, ZHUANG Lin, LU Jun-Tao. Proton Exchange Membrane Fuel Cells Completely Based on Pd-alloy Catalysts[J]. Chem. J. Chinese Universities, 2013, 34(1): 170.

[1]	CHU Yuyi, LAN Chang, LUO Ergui, LIU Changpeng, GE Junjie, XING Wei. Single-atom Cerium Sites Designed for Durable Oxygen Reduction Reaction Catalyst with Weak Fenton Effect [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220294.
[2]	CHENG Qian, YANG Bolong, WU Wenyi, XIANG Zhonghua. S-doped Fe-N-C as Catalysts for Highly Reactive Oxygen Reduction Reactions [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220341.
[3]	GU Yu, XI Baojuan, LI Jiangxiao, XIONG Shenglin. Structure Regulation of Single-atom Catalysts in Oxygen Reduction Reactions [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220036.
[4]	ZHANG Xiaoyu, XUE Dongping, DU Yu, JIANG Su, WEI Yifan, YAN Wenfu, XIA Huicong, ZHANG Jianan. MOF-derived Carbon-based Electrocatalysts Confinement Catalyst on O₂ Reduction and CO₂ Reduction Reactions [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210689.
[5]	HE Yujing, LI Jiale, WANG Dongyang, WANG Fuling, XIAO Zuoxu, CHEN Yanli. Zinc-based Activated Fe/Co/N Doped Biomass Carbon Electrocatalysts with High Oxygen Reduction Activity [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220475.
[6]	MA Jun, ZHONG Yang, ZHANG Shanshan, HUANG Yijun, ZHANG Lipeng, LI Yaping, SUN Xiaoming, XIA Zhenhai. Design and Theoretical Calculation of Heteroatoms Doped Graphdiyne Towards Efficiently Catalyzing Oxygen Reduction and Evolution Reactions [J]. Chem. J. Chinese Universities, 2021, 42(2): 624.
[7]	WANG Yuemin, MENG Qinglei, WANG Xian, GE Junjie, LIU Changpeng, XING Wei. Enhancement of Performance of Fe-N-C Catalysts by Copper and Sulfur Doping for the Oxygen Reduction Reaction [J]. Chem. J. Chinese Universities, 2020, 41(8): 1843.
[8]	YIN Wenjing, LIU Xiao, QIAN Huidong, ZOU Zhiqing. Preparation and Oxygen Reduction Performance of Fe, N co-Doped arbon Nanoplate with High Density of Active Sites^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1480.
[9]	LIU Jiaming,FU Kailin,ZHANG Ze,GUO Wei,PAN Mu. Ultra-low Pt Loading Cathodic Catalyst Layer Prepared on Textured Gas Diffusion Layer by Magnetron Sputtering Method for Hydrogen-oxygen Fuel Cells^† [J]. Chem. J. Chinese Universities, 2019, 40(3): 542.
[10]	XU Zhaoquan, MA Junhong, SHI Minhui, FENG Chao, XIE Yahong, MI Hongyu. Preparation and Application of a Novel Natural Product-based Fe and N Codoped Carbon Catalyst for Oxygen Reduction Reaction^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1532.
[11]	WANG Xiuli, HE Xingquan. Electrocatalytic Performance of Fe₉S₁₀ Nanoparticles Loaded Nitrogen and Sulphur Codoped Porous Carbon for Oxygen Reduction Reaction^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1524.
[12]	HUANG Jipei,LI Yi,YANG Shenhui,ZHOU Yazhou,CHENG Xiaonong,ZHU Jia,YANG Juan. Synthesis of Three-dimensional Pt-Ag Aerogels and Their Electrocatalytic Performance Toward Oxygen Reduction Reaction^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 1063.
[13]	DI Muxin, XIAO Guozheng, HUANG Peng, CAO Yihuan, ZHU Ying. Co/N Co-doped Carbon Nanotube/Graphene Composites as Efficient Electrocatalysts for Oxygen Reduction Reaction^† [J]. Chem. J. Chinese Universities, 2018, 39(2): 343.
[14]	LIU Pei, CHENG Qingqing, CHEN Chi, ZOU Liangliang, ZOU Zhiqing, YANG Hui. Preparation and Oxygen Reduction Reaction Catalytic Performance of Fe, N Co-doped Carbon Nanofibers with Encapsulated Iron Nitride^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2492.
[15]	KANG Huan, LI Shang, LIU Chang, GUO Wei, PAN Mu. Synthesis of Ordered Mesoporous Fe-N-C-PANI Catalyst via Self-assembly and Its Oxygen Reduction Reaction Activity in Acid Medium [J]. Chem. J. Chinese Universities, 2017, 38(8): 1423.

Proton Exchange Membrane Fuel Cells Completely Based on Pd-alloy Catalysts

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments