Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (2): 343.doi: 10.7503/cjcu20170288
• Physical Chemistry • Previous Articles Next Articles
DI Muxin1, XIAO Guozheng1, HUANG Peng2, CAO Yihuan2, ZHU Ying1,*()
Received:
2017-05-05
Online:
2018-02-10
Published:
2018-01-08
Contact:
ZHU Ying
E-mail:zhuying@buaa.edu.cn
Supported by:
CLC Number:
TrendMD:
DI Muxin, XIAO Guozheng, HUANG Peng, CAO Yihuan, ZHU Ying. Co/N Co-doped Carbon Nanotube/Graphene Composites as Efficient Electrocatalysts for Oxygen Reduction Reaction†[J]. Chem. J. Chinese Universities, 2018, 39(2): 343.
Fig.3 SEM images(A1—C1, A2—C2) and the corresponding C(A3—C3), Co(A4—C4) and N(A5—C5) elemental mappings of Co/N-CNT/Gr-800(A1—A5), Co/N-CNT/Gr-900(B1—B5) and Co/N-CNT/Gr-1000(C1—C5)
Fig.5 XPS spectra of Co-CNT/Gr(A1—A3) and Co/N-CNT/Gr-800(B1—B3) (A1), (B1) represent C1s spectra and the insets are the whole XPS spectra; (A2), (B2) and (A3), (B3) represent Co2p and N1s spectra, respectively.
Fig.6 CV curves of Pt/C(A), Co-CNT/Gr(B), Co/N-CNT/Gr-800(C), Co/N-CNT/Gr-900(D), Co/N-CNT/Gr-1000(E), LSV(F) and RRDE(G) curves of the Co-CNT/Gr, Co/N-CNT/Gr-X(X=800, 900, 1000) and Pt/C on GC electrodes(A)—(E) In O2-saturated(solid line) and N2-saturated(dashed line) 0.1 mol/L KOH at a scan rate of 50 mV/s; (F) in O2-saturated 0.1 mol/L KOH at a scan rate of 10 mV/s and a rotation rate of 1600 r/min; (G) in O2-saturated 0.1 mol/L KOH at a scan rate of 10 mV/s and a rotation rate of 1600 r/min.
Fig.7 Current-time curves of Co/N-CNT/Gr-800 and commercial Pt/C for electrodedurability(A) and tolerance to the methanol crossover(B) (A) in O2-saturated 0.1 mol/L KOH at -0.14 V and a rotation rate of 900 r/min; (B) in O2-saturated 0.1 mol/L KOH at -0.14 V and a rotation rate of 900 r/min. The arrow in (B) indicates the addition of 5 mL methanol into the electrochemical cell after about 100 s.
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