Synthesis and Crystal Structure of One-dimensional Chain Coordination Polymer [Mn(9-AC)2(4,4'-bpy)(H2O)2]n

Chem. J. Chinese Universities

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Synthesis and Crystal Structure of One-dimensional Chain Coordination Polymer [Mn(9-AC)₂(4,4'-bpy)(H₂O)₂]_n

ZHAO Guo-Li¹, WU Ying¹, YE Jun-Wei², YE Kai-Qi¹*

1. State Key laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China;
2. School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

Received:2007-08-13 Revised:1900-01-01 Online:2008-04-10 Published:2008-04-10
Contact: YE Kai-Qi

Abstract

Abstract: Hydrothermal reactions of Mn(Ⅱ) acetate, 4,4'-bipyridyl(bpy) with anthracene-9-carboxylic acid(9-HAC) resulted in a new coordination polymer [Mn(9-AC)₂(4,4'-bpy)(H₂O)₂]_n. The coordination polymer was characterized by ICP, IR, TGA and single-crystal X-ray diffraction analysis(Mo Kα). The crystal crystallizes in an orthorhombic system, space group Fdd2, a=1.66772(12) nm, b=3.36471(16) nm, c=1.1687(4) nm, V =6.558(2) nm³, Z=8, M_r=689.60, D_c=1.397 Mg/m³, R=0.0356, wR₂=0.0604. The Mn centers in the frameworks adopt slightly distorted octahedral coordination geometry, and is bridged by 4,4'-bpy ligands to form one-dimensional straight chain structure. The chain packing in the compound gives rise to three-dimensional structure based on weak coordination bond, hydrogen bonding interactions.

Key words: Hydrothermal synthesis, Coordination polymer, Crystal structure, Hydrogen bond

CLC Number:

O614

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ZHAO Guo-Li¹, WU Ying¹, YE Jun-Wei², YE Kai-Qi¹*. Synthesis and Crystal Structure of One-dimensional Chain Coordination Polymer [Mn(9-AC)₂(4,4'-bpy)(H₂O)₂]_n[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Crystal Structure of One-dimensional Chain Coordination Polymer [Mn(9-AC)₂(4,4'-bpy)(H₂O)₂]_n

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