Preparation of a Binder Free Electrode of NiAg Supported on Graphite Modified A4 Paper and Its Electrochemical Performance for H2O2 Reduction†

doi:10.7503/cjcu20170529

Abstract

Abstract:

An original electrode of NiAg supported on graphite modified A4 paper(NiAg@C/A) was prepared through electrodeposition and galvanic displacement without binder for H₂O₂ electroreduction. The morphology and phase composition of the as-prepared electrode were investigated by X-ray diffractometer(XRD), scanning electron microscope(SEM) and transmission electron microscope(TEM). And cyclic voltammetry and chronoamperometry were conducted to study the electrochemical performance of the NiAg@C/A electrode. The results reveal that the reduction current density of H₂O₂ on the NiAg@C/A electrode reaches 600 mA/cm in a solution of 0.6 mol/L H₂O₂ and 1 mol/L NaOH at -0.8 V. The NiAg@C/A electrode exhibits good stability toward the H₂O₂ reduction and is a good alternative for H₂O₂ electroreduction in the future.

Key words: NiAg, A4 Paper, Graphite, H₂O₂, Electroreduction

CLC Number:

O646

TrendMD:

CAI Zhuang,WANG Guiling,SONG Congying,YANG Xueying,HU Rong,YE Ke,ZHU Kai,CHENG Kui,YAN Jun,CAO Dianxue. Preparation of a Binder Free Electrode of NiAg Supported on Graphite Modified A4 Paper and Its Electrochemical Performance for H₂O₂ Reduction^†[J]. Chem. J. Chinese Universities, 2018, 39(5): 1041.

Figures/Tables 8

Fig.1 XRD patterns of C/A(a), Ni@C/A(b) and NiAg@C/A(c)

Fig.2 SEM images of C/A(A—C), Ni@C/A(D—F) and NiAg@C/A(G—I) in different magnifications

Fig.3 TEM(A, B, D) and HRTEM(C, E) images of Ni@C/A(A—C) and NiAg@C/A(D, E) and the SAED pattern(F) of NiAg@C/A

Fig.4 SEM image(A) and the corresponding element distribution(B—D) of NiAg@C/A Note:(B) Ni; (C) Ag; (D) C.

Fig.5 Cyclic voltammograms(CVs) of NiAg@C/A electrode with different replacement time in a solution of 1 mol/L NaOH+0.6 mol/L H2O2(A) and CVs of NiAg@C/A electrode in solutions of different NaOH concentrations with 0.6 mol/L H2O2(B) at a scan rate of 20 mV/s

Fig.6 CVs of C/A(a), Ni@C/A(b) and NiAg@C/A(c) electrodes in a solution of 1 mol/L NaOH+0.6 mol/L H2O2 at a scan rate of 20 mV/s Note:nset is the enlarged CV curve of C/A.

Fig.7 CVs of NiAg@C/A electrode in solutions of 1 mol/L NaOH with different H2O2 concentrations(A), and chronoamperometric curves of NiAg@C/A electrode in 1 mol/L NaOH and 0.6 mol/L H2O2 at different potentials(B)

Scheme 1 Mechanism of H2O2 electroreduction on the NiAg@C/A electrode

References 21

[1]	Ayse E., Int. J. Energ.Res., 2013, 37(12), 1488—1497
[2]	Song C., Yin X., Li B., Ye K., Zhu K., Cao D., Cheng K., Wang G., Dalton Trans., 2017, 46, 13845—13853
[3]	Yamada Y., Fukunishi Y., Yamazaki S., Fukuzumi S., Chem. Commun., 2010, 46(39), 7334—7336
[4]	Sanli A.E., Aytac A., Int. [J]. Hydrogen Energ., 2011, 36(1), 869—875
[5]	Yang F., Cao B., Tao Y., Cao D., Zhang Y., Electrochim. Acta, 2016, 210, 199—205
[6]	Wei J.L., Wang X. Y., Wang Y., Guo J., He P., Yang S., Fu N., Energ. Fuel., 2009, 23(8), 4037—4041
[7]	Lao S.J., Qin H. Y., Ye L.Q., Liu B. H., Li Z. P., [J]. Power Sources, 2010, 195(13), 4135—4138
[8]	Wang X., Ye K., Zhang H., Ma X., Zhu K., Cheng K., Wang G., Cao D., Int. J.Hydrogen Energ., 2017, 42(22), 15044—15053
[9]	Rajeshkhanna G., Umeshbabu E., Justin P., Ranga Rao G., [J]. Alloy Compd., 2017, 696, 947—955
[10]	Song C., Zhang D., Ye K., Wei J., Yang X., Wang Y., Shen Y., Cao D., Cheng K., Wang G., [J]. Electrocatal. Chem., 2017, 788, 74—82
[11]	Wang G.L., Hao S. Y., Lu T. H., Cao D. X., Yin C. L., Chem. [J]. Chinese Universities, 2010, 31(11), 2264—2267
	(王贵领, 郝世阳, 陆天虹, 曹殿学, 尹翠蕾. 高等学校化学学报, 2010, 31(11), 2264—2267)
[12]	Wang X., Ye K., Gao Y., Zhang H., Cheng K., Xiao X., Wang G., Cao D., [J]. Power Sources, 2016, 303, 278—286
[13]	Tian Y.M., Lei T., Wang G. L., Cao D. X., Chem. [J]. Chinese Universities, 2011, 32(10), 2382—2386
	(田永梅, 雷婷, 王贵领, 曹殿学. 高等学校化学学报, 2011, 32(10), 2382—2386)
[14]	Ye K., Zhang D., Wang X., Cheng K., Cao D., RSC Adv., 2015, 5(5), 3239—3247
[15]	Martins M., Sljukic B., Sequeira C.A. C., Soylu G. S. P., Bayrakceken Y. A., Bozkurt G., Sener T., Santos D. M. G., ECS Trans., 2016, 72(25), 57—64
[16]	Hasvold Ø., Storkersen N.J., Forseth S., Lian T., [J]. Power Sources, 2006, 162(2), 935—942
[17]	Chen B., Chen J., Yang L., Zhao G., Ding G., Chem. Res. Chinese Universities, 2016, 32(2), 278—283
[18]	Wang H., Shi X., Shi Y., Zhang W., Yao S., Chem. Res. Chinese Universities, 2017, 33(4), 638—642
[19]	Li Y., Cao D., Liu Y., Liu R., Yang F., Yin J., Wang G., Int. J.Hydrogen Energ., 2012, 37(18), 13611—13615
[20]	Yan P., Zhang D.M., Cheng K., Xu Y., Li Y. Y., Ye K., Cao D. X., Wang G. L., Chem. [J]. Chinese Universities, 2015, 36(9), 1801—1806
	(闫鹏, 张栋铭, 程魁, 徐阳, 李莹莹, 叶克, 曹殿学, 王贵领. 高等学校化学学报, 2015, 36(9), 1801—1806)
[21]	Zhang D., Cao D., Ye K., Yin J., Cheng K., Wang G., Electrochim. Acta, 2014, 139(26), 250—255

Related Articles 15

[1]	SONG Dewen, WANG Mingwang, WANG Yani, JIAO Zhenmei, NING Hui, WU Mingbo. Progress of CO₂ Electroreduction to Oxalic Acid [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220248.
[2]	YANG Dan, LIU Xu, DAI Yihu, ZHU Yan, YANG Yanhui. Research Progress in Electrocatalytic CO₂ Reduction Reaction over Gold Clusters [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220198.
[3]	LIU Xiaolei, LU Yongqiang, YOU Qi, LIU Guohui, YAO Wei, HU Riming, YAN Jixian, CUI Yu, YANG Xiaofeng, SUN Guoxin, JIANG Xuchuan. A 3-Hydroxythalidomide-based Ratiometric Fluorescent Probe for the Detection of H₂O₂ [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220070.
[4]	YAN Jiasen, HAN Xianying, DANG Zhaohan, LI Jiangang, HE Xiangming. Preparation and Performance of Paraffin/Expanded Graphite/Graphene Composite Phase Change Heat Storage Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220054.
[5]	ZHAO Junyu, WANG Chunbo, WANG Chengyang, ZHANG Ke, CONG Bing, YANG Lan, ZHAO Xiaogang, CHEN Chunhai. Preparation and Performance of Thermally Conductive Expanded Graphite/Polyetherimide Composites [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210800.
[6]	XU Mengyi, HUANG Xuewen, LI Xiaojie, WEI Wei, LIU Xiaoya. Fabrication of Biosensor Based on “Beads-on-a-String” Shaped Composite Nano-assembly Modified Screen Printed Electrode [J]. Chem. J. Chinese Universities, 2021, 42(6): 1768.
[7]	XIE Xingyu, ZHAO Yaxiang, ZHAO Lizhi, LI Rishun, WU Dihao, YE Hui, XIN Qingping, LI Hong, ZHANG Yuzhong. Colorimetric Detection Method for H₂O₂ Based on Two-dimensional Metal-organic Frameworks of Metalloporphyrin [J]. Chem. J. Chinese Universities, 2020, 41(8): 1776.
[8]	WANG Ruixue, YIN Dongmei, SONG Yongxin, SHAN Guiye. Preparation of CuS/Ag₂S Nanocomposite and the Peroxidase-like Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1218.
[9]	LIU Xinchao,ZHAO Yarong,YUAN Zhenyan,ZHOU Dan,LU Xinhuan,XIA Qinghua. Controllable Synthesis of Ti-Beta Zeolite and Efficiently Catalytic Epoxidation of Cyclohexene^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1222.
[10]	CHEN Yan,DONG Xuejiao,SHAN Guiye. Preparation of Liposome@Ag/Au Nanocomposites and Their Interaction with H₂ $O 2 †$ [J]. Chem. J. Chinese Universities, 2019, 40(4): 639.
[11]	LU Xinhuan,TAO Peipei,HUANG Fengfeng,ZHANG Xianggui,LIN Zhicheng,PAN Haijun,ZHANG Haifu,ZHOU Dan,XIA Qinghua. Nano-SnO₂ as Highly Efficient Catalyst for Epoxidation of Cyclic Olefins with Aqueous H₂ $O 2 †$ [J]. Chem. J. Chinese Universities, 2019, 40(3): 528.
[12]	Yujie LI,Yong LIU,Qizhi ZHAO,Chunman ZHENG. Study on Improving Storage Life of Lithium Ion Batteries Based on Construction of Polymer Functional Protective Film on the Surface of Graphite Anode ^† [J]. Chem. J. Chinese Universities, 2019, 40(12): 2542.
[13]	WANG Hui, PEI Yanbo, HU Shaozheng, MA Wentao, SHI Shuoyu. Synthesis and “Two Channel Pathway” Photocatalytic H₂O₂ Production Ability of Band Gap Tunable K⁺ Doped Graphitic Carbon Nitride^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1503.
[14]	XU Congbin, ZHANG Li, YANG Wenjie, SUN Hongliang, LIU Weijiang, JIAO Zhenhuan, JIAO Chunlei, LIN Aijun. Nitrate Removal by Expanded Graphite Loaded with Zero-valent Iron:Performance and Mechanism [J]. Chem. J. Chinese Universities, 2017, 38(8): 1415.
[15]	JIAO Chunlei, XU Congbin, LI Shuyan, YANG Wenjie, SUN Hongliang, LIU Weijiang, JIAO Zhenhuan, LIN Aijun. Preparation and Arsenic Removal Mechanism of Iron Oxyhydroxide/expanded Graphite Composite Material [J]. Chem. J. Chinese Universities, 2017, 38(8): 1316.

Preparation of a Binder Free Electrode of NiAg Supported on Graphite Modified A4 Paper and Its Electrochemical Performance for H₂O₂ Reduction^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 21

Related Articles 15

Recommended Articles

Metrics

Comments