Synthesis of a New Open-framework Aluminophosphate and the Co-templating Effect in the Crystallization†

doi:10.7503/cjcu20170038

Abstract

Abstract:

By heating the initial mixture with the molar composition of n(Al₂O₃)∶n(P₂O₅)∶n(1,2-DAP)∶n(H₂O)=1∶6∶x∶139(1,2-DAP refers to 1,2-diaminopropane) at 180 ℃, a new three-dimensional open-framework aluminophosphate(compound 1) and a two-dimensional layered aluminophosphate APDAP₁₂-150 were obtained at x=5.5 and x=7.5, respectively. The framework topology of compound 1 is the same as that of AlPO-CJ31, a three-dimensional open-framework aluminophosphate directed by the template of diethylenetriamine. By combing the results of powder X-ray diffraction analysis(XRD), elemental analysis(C, H, N) and TG-DTA analysis, the composition of compound 1 was determined and the co-templating effect of protonated water was confirmed.

Key words: Zeolite, Aluminophosphate, Co-template directing effect

CLC Number:

O611.4

TrendMD:

WANG Aitian, SUN Yangyang, XU Ruren, YAN Wenfu. Synthesis of a New Open-framework Aluminophosphate and the Co-templating Effect in the Crystallization^†[J]. Chem. J. Chinese Universities, 2017, 38(5): 701.

Figures/Tables 4

Fig.1 Aluminophosphates directed by diethylenetriamine and 1,2-diaminopropane

Fig.2 Experimental XRD powder pattern of compound 1(a) and simulated one of AlPO-CJ31(b)(A) and experimental powder XRD pattern(a) and simulated one(b) of APDAP12-150(B)

Fig.3 SEM images of compound 1(A) and APDAP12-150(B)

Fig.4 TG-DTA curves of compound 1

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