Synthesis and Crystal Structure of Four Silver Complexes with 1,2-Bis(2-amino-phenoxy)ethane

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (9): 2187.

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Synthesis and Crystal Structure of Four Silver Complexes with 1,2-Bis(2-amino-phenoxy)ethane

ZHANG Qi-Long², ZHANG Yun-Qian¹, ZHU Bi-Xue^1*

1. Key Laboratory of Macrocycle and Supramolecular Chemistry of Guizhou Province, College of Chemistry, Guizhou University, Guiyang 550025, China;
2. Department of Chemistry, Guiyang Medical College, Guiyang 550004, China

Received:2011-03-29 Revised:2011-05-31 Online:2011-09-10 Published:2011-08-11
Contact: ZHU Bi-Xue E-mail:sci.bxzhu@gzu.edu.cn
Supported by:
国家自然科学基金(批准号: 21061003)和贵州省国际合作重点项目(批准号: 黔科合外G字[2009]700104)资助.

Abstract

Abstract: The four complexes were synthesized from the reaction of 1,2-(2-aminophenoxy)ethane with AgX (X=PF6-, CF3SO3-, NO3- and AgSbF6-) respectively, and characterized by elemental analysis, FTIR and single crystal X-ray diffraction. The results of structural analysis indicate that both complexes 1 and 2 are dinuclear silver (I) complexes, while both complexes 3 and 4 are coordination polymers. The complex 1 is a cryptand, and 2 is a torsional structure formed by Ag－Ag bridging, 3 is 1D zigzag chain, and 4 is 3D porous frameworks. In the four complexes, the inorganic counter anion don’t coordinate with Ag(I).

Key words: 1,2-(2-Aminophenoxy)ethane, Silver(I), Crystal structure

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ZHANG Qi-Long, ZHANG Yun-Qian, ZHU Bi-Xue*. Synthesis and Crystal Structure of Four Silver Complexes with 1,2-Bis(2-amino-phenoxy)ethane[J]. Chem. J. Chinese Universities, 2011, 32(9): 2187.

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Synthesis and Crystal Structure of Four Silver Complexes with 1,2-Bis(2-amino-phenoxy)ethane

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