Synthesis, Structure and Luminescence Property of Transition Metal Complexes with 1,3-Di(4-pyridyl)-propane and 1,2-Benzenedicarboxylic Acid†

doi:10.7503/cjcu20160958

Abstract

Abstract:

Taking 1,3-di(4-pyridyl)-propane(bpp) and 1,2-benzenedicarboxylic acid(1,2-H₂bdc) as ligands, three new transition metal complexes, M₂(1,2-bdc)₂(bpp)₂·2H₂O[M(Ⅱ)=Co(1), Ni(2)] and Cd(1,2-bdc)(bpp)·H₂O(3), were obtained. Complexes 1 and 2 crystallize in monoclinic crystal system with space group P2₁ and show 3D structures with {6⁵·8} topology. There are two M(Ⅱ) centers with the similar coordination environments in complexes 1 and 2. Each M(Ⅱ) center is six-coordinated to three oxygen atoms from two 1,2-bdc ligands, two nitrogen atoms from bpp ligands and one water molecule in a distorted octahedral arrangement. The 1,2-bdc ligand adopts monodentate bridging/bidentate chelating mode to link two metal centers to form M1-(bpp)-M1 right-handed-helical chain. The bpp ligand adopts Trans-Gauche(TG) conformation and connects adjacent M(Ⅱ) centers to form M1-(bpp)-M1 and M2-(bpp)-M2 chains. These three kinds of chains are woven together to form a 3D framework. Complex 3 crystallizes in monoclinic crystal system with space group P2₁/c and shows a 2D structure. The Cd(Ⅱ) is in distorted pentagonal bipyramidal polyhedron with four oxygen atoms of two 1,2-bdc ligands, two nitrogen atoms of bpp ligand and one water molecule. The 1,2-bdc ligand adopts bi(bidentate chelating) mode to link Cd(Ⅱ) centers to form Cd-(1,2-bdc)-Cd chain. The bpp ligand adopts TG conformation and connects Cd(Ⅱ) centers to form Cd-(bpp)-Cd chain. The two kinds of chains with shared Cd(Ⅱ) are alternately arranged to form a 2D structure. Complex 3 shows strong ligand-based fluorescence with maximum emission at 408 nm, which is attributed to π^*-π transition of the ligands. Different organic small molecules have different effects on the fluorescence intensity of complex 3, and aniline has a significant quenching effect, thus complex 3 can be used for the selective detection of aniline through fluorescence quenching mechanism.

Key words: Transition metal complex, 1, 3-Di(4-pyridyl)-propane, 1, 2-Benzenedicarboxylic acid, Crystal structure, Fluorescence

TrendMD:

WANG Qiushuang, ZHENG Xiaoli, QU Xianglong, LI Rui, LI Xia. Synthesis, Structure and Luminescence Property of Transition Metal Complexes with 1,3-Di(4-pyridyl)-propane and 1,2-Benzenedicarboxylic Acid^†[J]. Chem. J. Chinese Universities, 2017, 38(7): 1125.

Figures/Tables 11

References 41

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Complex	1	2	3
Empirical formula	C₄₂H₄₀N₄O₁₀Co₂	C₄₂H₄₀N₄O₁₀Ni₂	C₂₁H₂₀N₂O₅Cd
Formula weight	878.64	878.20	492.79
Temperature/K	120(2)	120(2)	120(2)
Crystal system	Monoclinic	Monoclinic	Monoclinic
Space group	P2₁	P2₁	P2₁/c
a/nm	1.16755(2)	1.1609(3)	1.04635(8)
b/nm	1.4003(2)	1.3986(3)	1.01448(8)
c/nm	1.18421(2)	1.1847(3)	1.87662(1)
β/(°)	96.298(2)	96.632(3)	109.661(3)
V/nm³	1.9244(5)	1.9107(7)	1.8759(2)
Z	2	2	4
D_c/(g·cm^-3)	1.516	1.526	1.745
Absorption coefficient/mm^-1	0.928	1.052	1.202
F(000)	908	912	992
Crystal size/mm	0.38×0.34×0.30	0.42×0.15×0.10	0.15×0.10×0.07
θ range for data collection/(°)	1.730—25.249	2.26—25.25	2.07—27.63
Limiting indices	-14≤h≤10, -16≤k≤16,	-13≤h≤13, -16≤k≤8,	-13≤h≤12, -13≤k≤13,
	-12≤l≤14	-14≤l≤13	-24≤l≤20
Reflections collected	9762	9035	10882
R_int	0.0220	0.0322	0.0311
Data/restraints/parameters	6637/7/535	4556/31/554	4307/39/280
Goodness-of-fit on F²	1.028	1.062	1.025
Final R indices[I>2σ(I)]	R₁=0.0373, wR₂=0.0887	R₁=0.0501, wR₂= 0.1463	R₁=0.0284, wR₂= 0.0604
R indices(all data)	R₁=0.0405, wR₂=0.0907	R₁=0.0525, wR₂=0.1478	R₁=0.0358, wR₂= 0.0636
CCDC No.	1522654	1522656	1522655

Complex	1	2	3
Empirical formula	C₄₂H₄₀N₄O₁₀Co₂	C₄₂H₄₀N₄O₁₀Ni₂	C₂₁H₂₀N₂O₅Cd
Formula weight	878.64	878.20	492.79
Temperature/K	120(2)	120(2)	120(2)
Crystal system	Monoclinic	Monoclinic	Monoclinic
Space group	P2₁	P2₁	P2₁/c
a/nm	1.16755(2)	1.1609(3)	1.04635(8)
b/nm	1.4003(2)	1.3986(3)	1.01448(8)
c/nm	1.18421(2)	1.1847(3)	1.87662(1)
β/(°)	96.298(2)	96.632(3)	109.661(3)
V/nm³	1.9244(5)	1.9107(7)	1.8759(2)
Z	2	2	4
D_c/(g·cm^-3)	1.516	1.526	1.745
Absorption coefficient/mm^-1	0.928	1.052	1.202
F(000)	908	912	992
Crystal size/mm	0.38×0.34×0.30	0.42×0.15×0.10	0.15×0.10×0.07
θ range for data collection/(°)	1.730—25.249	2.26—25.25	2.07—27.63
Limiting indices	-14≤h≤10, -16≤k≤16,	-13≤h≤13, -16≤k≤8,	-13≤h≤12, -13≤k≤13,
	-12≤l≤14	-14≤l≤13	-24≤l≤20
Reflections collected	9762	9035	10882
R_int	0.0220	0.0322	0.0311
Data/restraints/parameters	6637/7/535	4556/31/554	4307/39/280
Goodness-of-fit on F²	1.028	1.062	1.025
Final R indices[I>2σ(I)]	R₁=0.0373, wR₂=0.0887	R₁=0.0501, wR₂= 0.1463	R₁=0.0284, wR₂= 0.0604
R indices(all data)	R₁=0.0405, wR₂=0.0907	R₁=0.0525, wR₂=0.1478	R₁=0.0358, wR₂= 0.0636
CCDC No.	1522654	1522656	1522655

Co1—O6	0.2020(4)	Co1—O1	0.2153(4)	Co2—O8	0.2102(4)
Co1—N2A	0.2105(5)	Co1—O2	0.2212(4)	Co2—N3	0.2112(5)
Co1—N1	0.2110(5)	Co2—O4B	0.1987(4)	Co2—O10	0.2185(4)
Co1—O5	0.2152(4)	Co2—N4C	0.2095(5)	Co2—O9	0.2237(4)
O6—Co1—N2A	100.21(18)	O6—Co1—O2	94.71(16)	O8—Co2—N3	94.64(16)
O6—Co1—N1	92.04(17)	N2A—Co1—O2	164.30(16)	O4B—Co2—O10	89.72(16)
N2A—Co1—N1	92.14(18)	N1—Co1—O2	92.18(17)	N4C—Co2—O10	84.56(17)
O6—Co1—O5	90.58(16)	O5—Co1—O2	89.73(16)	O8—Co2—O10	85.50(15)
N2A—Co1—O5	85.30(17)	O1—Co1—O2	60.59(14)	N3—Co2—O10	179.62(18)
N1—Co1—O5	176.63(18)	O4B—Co2—N4C	100.76(18)	O4B—Co2—O9	97.62(15)
O6—Co1—O1	154.37(16)	O4B—Co2—O8	158.35(16)	N4C—Co2—O9	159.14(16)
N2A—Co1—O1	103.95(17)	N4C—Co2—O8	99.79(17)	O8—Co2—O9	61.00(14)
N1—Co1—O1	95.45(17)	O4B—Co2—N3	90.28(17)	N3—Co2—O9	94.61(16)
O5—Co1—O1	83.07(15)	N4C—Co2—N3	95.07(18)	O10—Co2—O9	85.76(15)

Co1—O6	0.2020(4)	Co1—O1	0.2153(4)	Co2—O8	0.2102(4)
Co1—N2A	0.2105(5)	Co1—O2	0.2212(4)	Co2—N3	0.2112(5)
Co1—N1	0.2110(5)	Co2—O4B	0.1987(4)	Co2—O10	0.2185(4)
Co1—O5	0.2152(4)	Co2—N4C	0.2095(5)	Co2—O9	0.2237(4)
O6—Co1—N2A	100.21(18)	O6—Co1—O2	94.71(16)	O8—Co2—N3	94.64(16)
O6—Co1—N1	92.04(17)	N2A—Co1—O2	164.30(16)	O4B—Co2—O10	89.72(16)
N2A—Co1—N1	92.14(18)	N1—Co1—O2	92.18(17)	N4C—Co2—O10	84.56(17)
O6—Co1—O5	90.58(16)	O5—Co1—O2	89.73(16)	O8—Co2—O10	85.50(15)
N2A—Co1—O5	85.30(17)	O1—Co1—O2	60.59(14)	N3—Co2—O10	179.62(18)
N1—Co1—O5	176.63(18)	O4B—Co2—N4C	100.76(18)	O4B—Co2—O9	97.62(15)
O6—Co1—O1	154.37(16)	O4B—Co2—O8	158.35(16)	N4C—Co2—O9	159.14(16)
N2A—Co1—O1	103.95(17)	N4C—Co2—O8	99.79(17)	O8—Co2—O9	61.00(14)
N1—Co1—O1	95.45(17)	O4B—Co2—N3	90.28(17)	N3—Co2—O9	94.61(16)
O5—Co1—O1	83.07(15)	N4C—Co2—N3	95.07(18)	O10—Co2—O9	85.76(15)

Ni1—O6	0.2009(6)	Ni1—O1	0.2128(5)	Ni2—N3	0.2075(6)
Ni1—N2A	0.2053(7)	Ni1—O2	0.2145(5)	Ni2—O8	0.2080(5)
Ni1—N1	0.2066(6)	Ni2—O4B	0.1985(5)	Ni2—O10	0.2117(5)
Ni1—O5	0.2108(6)	Ni2—N4C	0.2048(7)	Ni2—O9	0.2178(5)
O6—Ni1—N2A	98.3(2)	O6—Ni1—O2	96.6(2)	N3—Ni2—O8	93.5(2)
O6—Ni1—N1	91.6(2)	N2A—Ni1—O2	164.2(2)	O4B—Ni2—O10	89.8(2)
N2A—Ni1—N1	91.5(3)	N1—Ni1—O2	93.2(2)	N4C—Ni2—O10	85.0(2)
O6—Ni1—O5	90.5(2)	O5—Ni1—O2	88.8(2)	N3—Ni2—O10	179.6(3)
N2A—Ni1—O5	85.9(2)	O1—Ni1—O2	62.2(2)	O8—Ni2—O10	86.6(2)
N1—Ni1—O5	176.9(3)	O4B—Ni2—N4C	97.6(2)	O4B—Ni2—O9	100.1(2)
O6—Ni1—O1	158.1(2)	O4B—Ni2—N3	90.3(2)	N4C—Ni2—O9	160.3(2)
N2A—Ni1—O1	102.4(2)	N4C—Ni2—N3	94.6(3)	N3—Ni2—O9	94.0(2)
N1—Ni1—O1	94.8(2)	O4B—Ni2—O8	162.1(2)	O8—Ni2—O9	62.2(2)
O5—Ni1—O1	84.0(2)	N4C—Ni2—O8	99.5(2)	O10—Ni2—O9	86.4(2)