Solvent Effect for the Synthesis of Metal\|organic Framework

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (3): 590.

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Solvent Effect for the Synthesis of Metal\|organic Framework

ZHAO Huan-Yu, JIN Zhao, SUN Fu-Xing, ZHU Guang-Shan*

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Received:2010-10-28 Revised:2010-12-24 Online:2011-03-10 Published:2011-02-23
Contact: ZHU Guang-Shan E-mail:zhugs@mail.jlu.edu.cn
Supported by:
国家自然科学基金(批准号: 20831002, 20625102, 20571030)资助.

Abstract

Abstract: Two novel compounds Cd(OBA)(bipy)?DMF (1) and Cd(OBA)(bipy) (2) (OBA = 4,4’-Oxybis(benzoic acid), bipy = 4,4'-bipyridine) were synthesized under hydrothermal (solvothermal) by using DMF and water as solvent respectively. X-ray diffraction analyses reveal that both the compounds are in the monoclinic and C2/c space group Compound 1 exhibits a two-dimension framework and compound 2 is a three-dimension framework.

Key words: Solvent effect, metal-organic framework, 4,4’-Oxybis(benzoic acid)

CLC Number:

O611.4

TrendMD:

ZHAO Huan-Yu, JIN Zhao, SUN Fu-Xing, ZHU Guang-Shan*. Solvent Effect for the Synthesis of Metal\|organic Framework[J]. Chem. J. Chinese Universities, 2011, 32(3): 590.

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Solvent Effect for the Synthesis of Metal\|organic Framework

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