Rhodamine-Based Fluorescence Probe for Pd2+ Detection

Abstract

Abstract: A new rhodamine-based derivative modified with allyl group, RPd4, was synthesized as fluorescence-enhanced probe with excellent selectivity for Pd²⁺ and good anti-jamming ability over other cations. The fluorescence intensitiy was linearly proportional to the amount of Pd²⁺ added in μmol/L level with a detection limit of 0.51 μmol/L. With the pK_a of 3.81±0.02, it can be used for Pd²⁺ detection in neutral pH range. The colorimetric and fluorimetric response between RPd4 and Pd²⁺ can provide a convenient method for visual detection of Pd²⁺.

Key words: Fluorescence probe, Rhodamine, Allyl, Fluorescence-enhanced

TrendMD:

LI Hong-Lin, FAN Jiang-Li*, LIU Xiao-Jian, SUN Shi-Guo, PENG Xiao-Jun. Rhodamine-Based Fluorescence Probe for Pd²⁺ Detection[J]. Chem. J. Chinese Universities, 2010, 31(9): 1725.

References

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Rhodamine-Based Fluorescence Probe for Pd²⁺ Detection

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