Hydrothermal Synthesis and Structure Characterization of a Piperazine-templated Two-dimenisional Cerium Sulfate, [C4N2H12]3[Ce2(SO4)6(H2O)2

Chem. J. Chinese Universities

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Hydrothermal Synthesis and Structure Characterization of a Piperazine-templated Two-dimenisional Cerium Sulfate, [C₄N₂H₁₂]₃[Ce₂(SO₄)₆(H₂O)₂

XIN Ming-Hong, WANG Ying, ZHU Guang-Shan, SUN Jin-Yu, FANG Qian-Rong, XUE Ming, TIAN Ge, QIU Shi-Lun*

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Received:2006-09-10 Revised:1900-01-01 Online:2007-07-10 Published:2007-07-10
Contact: QIU Shi-Lun

Abstract

Abstract:

A cerium sulfate hydrate, [C₄N₂H₁₂]₃[Ce₂(SO₄)₆(H₂O)₂]·H₂O, was synthesized via the hydrothermal method with piperazine as a template and characterized by single-crystal X-ray diffraction. The compound crystallizes in monoclinic system, space group P2₁/c with cell parameters a=0.66335(10) nm, b=2.8088(4) nm, c=1.02212(15) nm, β=96.160(2)°, final R indices [I>2σ(I)], R₁=0.0466 and wR₂=0.1226. The compound exhibits a corrugated layer structure, which is constructed from inorganic anionic sheets of cerium sulfates with diprotonated piperazine cations and water molecules locating between the layers. An eight-membered ring is created in the layer with a diprotonated piperazine molecule locating in it. The thermal behavior of the compound was also examined.

Key words: Cerium sulfate, Hydrothermal synthesis, Crystal structure, Two-dimensional layer

CLC Number:

O614

TrendMD:

XIN Ming-Hong, WANG Ying, ZHU Guang-Shan, SUN Jin-Yu, FANG Qian-Rong, XUE Ming, TIAN Ge, QIU Shi-Lun*. Hydrothermal Synthesis and Structure Characterization of a Piperazine-templated Two-dimenisional Cerium Sulfate, [C₄N₂H₁₂]₃[Ce₂(SO₄)₆(H₂O)₂[J]. Chem. J. Chinese Universities, doi: .

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Hydrothermal Synthesis and Structure Characterization of a Piperazine-templated Two-dimenisional Cerium Sulfate, [C₄N₂H₁₂]₃[Ce₂(SO₄)₆(H₂O)₂

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