Hydrothermal Preparation of Nanostructured MnO2 and Morphological and Crystalline Evolution

Chem. J. Chinese Universities

Previous Articles Next Articles

Hydrothermal Preparation of Nanostructured MnO₂ and Morphological and Crystalline Evolution

LI Ying-Pin, ZHOU Xiao-Quan, ZHOU Hui-Jing, SHEN Zhu-Rui, CHEN Tie-Hong*

Department of Materials Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

Received:2007-01-22 Revised:1900-01-01 Online:2007-07-10 Published:2007-07-10
Contact: CHEN Tie-Hong

Abstract

Abstract:

Manganese dioxides with various morphologies were prepared with a common hydrothermal method without any templates or additives. The morphological evolution was accompanied with the conversion of the polymorphic forms, gradually from γ-type to β-type. Meanwhile, MnO₂ microspheres, urchinlike nanostructures and nanowires were successfully synthesized. The products were characterized via X-ray powder diffraction, X-ray photoelectron spectroscopy, scanning electron microscope and transmission electron microscope. The process can be explained with Ostwald-Ripening mechanism.

Key words: MnO₂, Hydrothermal preparation, Crystal type, Core-shell structure, Nanowires

CLC Number:

O614

TrendMD:

LI Ying-Pin, ZHOU Xiao-Quan, ZHOU Hui-Jing, SHEN Zhu-Rui, CHEN Tie-Hong*. Hydrothermal Preparation of Nanostructured MnO₂ and Morphological and Crystalline Evolution[J]. Chem. J. Chinese Universities, doi: .

[1]	JIANG Shenghan, CAO Changlin, XIAO Liren, YANG Tang, QIAN Qingrong, CHEN Qinghua. Preparation of Composite Semiconductor Micro-sheets with UV Shielding Performance and Its Application in Polypropylene [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220071.
[2]	FAN Xiaohui, WANG Yang, YANG Yuanyuan, ZHANG Yuhong. Preparation and Properties of Gold Nanocages/Hyaluronic Acid Core-shell Nanocarriers with pH/Enzyme/ Photothermal Multiple Responses [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210855.
[3]	XIA Dacheng, ZHOU Rui, TU Bo, CAI Zhiwei, GAO Nan, JI Xiaoxu, CHANG Gang, REN Xiaoming, HE Yunbin. Fabrication of Ag/Au Nanowires Array as a SERS Substrate for High-sensitivity Malachite Green Detection [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210731.
[4]	GUO Biao, ZHAO Chencan, LIU Xinxin, YU Zhou, ZHOU Lijing, YUAN Hongming, ZHAO Zhen. Effects of Surface Hydrothermal Carbon Layer on the Photocatalytic Activity of Magnetic NiFe₂O₄ Octahedron [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220472.
[5]	TAO Xingfu, HAN Chenglong, YANG Yang, LIU Kun. Synthesis of Aluminum Nanoparticles@Polymer Core-shell Nanostructures by Surface-initiated Polymerization [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220367.
[6]	LI Botian,SHAO Wei,XIAO Da,ZHOU Xue,DONG Junwei,TANG Liming. Polypyrrole Nanowire Gels Based on Templating Fabrication and Their Energy Storage and Electrochemical Sensing Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 183.
[7]	LI Ren, ZHAO Jianwei, HOU Jin, HE Yuanyuan, CHENG Na. Effect of the Convex and the Concave Microstructures in the Metallic Nanowires on the Initial Deformation Behavior^† [J]. Chem. J. Chinese Universities, 2018, 39(3): 514.
[8]	QIU Jiaxin,JIANG Qi,GAO Yike,PENG Junqi,DUAN Zhihong,LU Xiaoying. Electrochemical Studies on the Working Mechanism of Lithium-rich Manganese Based Material Coated by MnO₂ ^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2238.
[9]	ZHANG Long, WAN Xiaona, DUAN Wenjing, QIU Hu, HOU Jieqiong, WANG Xiaorui, LI Hui, DU Xueyan. Synthesis and Microwave Absorption Performance of Fe₃O₄@PPy@PANI Composites^† [J]. Chem. J. Chinese Universities, 2018, 39(1): 185.
[10]	SHI Yanlong, FENG Xiaojuan, WANG Suiqian, FENG Chunchun. Fabrication of Superhydrophobic Film of Co(OH)₂CO₃ Nanowires and Its Anticorrosion^† [J]. Chem. J. Chinese Universities, 2017, 38(3): 456.
[11]	LI Xingsheng, HE Wenxiu, ZHANG Yongqiang, YU Huiying, LI Ziqing. Preparation by Phase Transformation Method and Electrochemical Performance of β-Ni(OH)₂ Nanowires^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 261.
[12]	WANG Xiaodan, XU Dandan, LÜ Weizhong, LIU Jingyuan, LIU Qi, JING Xiaoyan, WANG Jun. Preparation and Drug Release of Anti-cancer Fe₃O₄@ZIF-8@PA System Loaded with Drug^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 1927.
[13]	XU Kaige, ZHANG Di, LEI Jie, PENG Yage, PENG Juan, JIN Xiaoyong. Au Nanowires-MWCNTs Modified Electrode for Catalyzing the Oxidization of Glucose^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1864.
[14]	LIU Jiaxin, SONG Yian, HUANG Yudong. PdZn Alloy Nanoparticles Epitaxial Growth on ZnO Nanowires for Methanol Steam Reforming^† [J]. Chem. J. Chinese Universities, 2016, 37(7): 1372.
[15]	HUO Hailing, LÜ Liyun, WANG Hong. One-pot Synthesis of Homogeneous Core-shell ZnS Structures and Their Photocatalytic Properties^† [J]. Chem. J. Chinese Universities, 2015, 36(5): 939.

Hydrothermal Preparation of Nanostructured MnO₂ and Morphological and Crystalline Evolution

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments