Investigation on Second-order Nonlinear Optical Property of Amino Acid Bridged Chiral Porphyrin Dimmer

Chem. J. Chinese Universities

• 研究论文 • Previous Articles Next Articles

Investigation on Second-order Nonlinear Optical Property of Amino Acid Bridged Chiral Porphyrin Dimmer

YING Xiao¹, ZHANG Xin-Wei¹, LIAO Shi-Jun², LIU Hai-Yang², CHANG Chi-Kwong³

1. Department of Applied Physics, South China University of Technology;
2. Department of Applied Chemistry, South China University of Technology, Guangzhou 510641, China;
3. Department of Chemistry, The Hong Kong University of Science and Technology, Hong Kong, China

Received:2006-01-18 Revised:1900-01-01 Online:2006-12-10 Published:2006-12-10
Contact: LIU Hai-Yang

Abstract

Abstract: Geometries of amino acid bridged bis-porphyrin 1,2,3,4 and their zinc(Ⅱ) complexes were optimized at semiempirical PM3 quantum chemistry level. Static second-order NLO coefficients of these bis-porphyrins were then calculated by TDHF/PM3 method. The calculation results show that all L-type amino acid bridged bis-porphyrins exhibit right-handed helix structures. Within the electric-dipole approximation, second-order NLO coefficients β of these bis-porphyrins change little with the varying of amino acid side chains. However, the second-order NLO chiral components β_xyz of amino acid bridged bis-porphyrins are significantly different. The chiral component β_xyz and the helix structure parameter r²ζ/L⁴matches β_xyz∝r²ζ/L⁴, indicating the second-order chiral NLO response of helix chiral bis-porphyrins could be well described by one-electron helical model theory. The analysis of β components indicates that these amino acid bridged bis-porphyrins are multipolar molecules with ‖β_J₌₃‖/‖β_J₌₁‖≈11—17. In comparison to free-base helix bis-porphyrin, the insertion of Zn(Ⅱ) ion favors the accretion of the second-order NLO dipolar component and chiral component β_xyz of molecules.

Key words: Amino acid, Chiral bis-porphyrin, Second-order NLO, TDHF/PM3

CLC Number:

O641.12

TrendMD:

YING Xiao¹, ZHANG Xin-Wei¹, LIAO Shi-Jun², LIU Hai-Yang², CHANG Chi-Kwong³. Investigation on Second-order Nonlinear Optical Property of Amino Acid Bridged Chiral Porphyrin Dimmer[J]. Chem. J. Chinese Universities, doi: .

[1]	TIAN Xueqin, MO Zheng, DING Xin, WU Pengyan, WANG Yu, WANG Jian. A Squaramide-containing Luminescent Metal-organic Framework as a High Selective Sensor for Histidine [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210589.
[2]	LIANG Longqi, CHEN Cailing, YU Ying, LI Yuxin, LI Chunguang, SHI Zhan. Synthesis, Luminescence and Cell Imaging Properties of Amino Acid Capped YVO₄∶Eu Nanoparticles ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 425.
[3]	ZHANG Ye,WU Weihui,ZONG Liang,DONG Junjun. Carbonate Handle Modified Wang Resin and Its Function^† [J]. Chem. J. Chinese Universities, 2019, 40(3): 462.
[4]	XU Yan,LIU Cui,HAN Chengjuan,PAN Mingyu,SUN Zhaoqi,HAN Bingyu,YANG Zhongzhi. Development of Polarization Force Field for Guanine and Amino Acid Residues Systems^† [J]. Chem. J. Chinese Universities, 2019, 40(2): 288.
[5]	BAI Lei,HUO Shuhui,CHEN Jing,LU Xiaoquan. Squaramide Fluorescence Probe for Chiral Recognition of α-Amino Acids^† [J]. Chem. J. Chinese Universities, 2019, 40(1): 41.
[6]	HAN Bingyu, LI Yue, LIU Cui. Investigation on the Hydrogen Bonding Interaction Between Amino Acid Side Chains and Base Pairs Containing Oxidized Guanine^† [J]. Chem. J. Chinese Universities, 2017, 38(6): 1068.
[7]	HUANG Yandong, WU Ruofei, CHU Yanqiu, DING Chuanfan. Effect of Side Chain of α-Amino Acids and Esters on the Stability Constants for β-Cyclodextrin Complexes^† [J]. Chem. J. Chinese Universities, 2017, 38(5): 743.
[8]	ZHAO Jian, DU Jing, LIU Shuo, YANG Zhongzhi, ZHAO Dongxia, LIU Cui. Theoretical Studies on the Effect of Amino Acid Side Chains on Hydrogen Bonding for G:C in Aqueous Solution^† [J]. Chem. J. Chinese Universities, 2016, 37(9): 1686.
[9]	YANG Zechuan, LI Fan, HUANG Qingrong, ZHANG Guo, SHI Tongfei. Synthesis and Properties of the Amino Acid Functionalized Curcumin/His-Pectin Colloidal Particles^† [J]. Chem. J. Chinese Universities, 2016, 37(2): 381.
[10]	WEI Yana, ZHANG Xincun, LI Hui, XU Qian, YUE Fan, WANG Jide. Relationship Between Reversible Oxygenation and Catalytic Properties of Amino Acid Cobalt Complexes^† [J]. Chem. J. Chinese Universities, 2016, 37(2): 354.
[11]	XUE Peng, WEI Yana, YUE Fan, ZHANG Yi, WANG Jide. Effects of Functional Groups in α-Amino Acids on Reversible Oxygenation Performance of Co(Ⅱ) Complexes^† [J]. Chem. J. Chinese Universities, 2016, 37(10): 1769.
[12]	HU Can, CHEN Yi. Dissolution/diffusion-based Injection for Fast Separation of Epinephrine and Norepinephrine by Short Capillary Electrophoresis^† [J]. Chem. J. Chinese Universities, 2015, 36(9): 1681.
[13]	AN Dong, YE Zhiwen, ZHOU Mi. Synthesis and Anti-tumor Activity of Novel Amino Acid Glyceroglycolipid^† [J]. Chem. J. Chinese Universities, 2015, 36(12): 2427.
[14]	XU Linxu, CUI Fang, WANG Hao, YAO Tongjie, CUI Tieyu. Synthesis and Optic Properties of Sulfide/Silica Nanocomposite Material^† [J]. Chem. J. Chinese Universities, 2014, 35(12): 2694.
[15]	WEN Hong-Mei, ZHANG Xu, LI Hui, YUE Fan, WANG Ji-De. Contrast Study of the Oxygenation of Co(Ⅱ) Complexes with Different Bi-/Poly-dentate Ligands [J]. Chem. J. Chinese Universities, 2013, 34(10): 2262.

Investigation on Second-order Nonlinear Optical Property of Amino Acid Bridged Chiral Porphyrin Dimmer

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments