Electrooxidation of 3-Picoline in Acetone/Water Mixed Solvents

Chem. J. Chinese Universities

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Electrooxidation of 3-Picoline in Acetone/Water Mixed Solvents

XU Yu-Ling, CAO Xue-Jing, ZHANG Heng-Bin, ZHANG Yu-Min, LI Ke-Chang

College of Chemistry, Jilin University, Changchun 130021, China

Received:2005-10-28 Revised:1900-01-01 Online:2006-11-10 Published:2006-11-10
Contact: ZHANG Heng-Bin

Abstract

Abstract: In an electrolytic cell with proton exchange membrane as the diaphragm, it was found from the electrooxidation of 3-picoline at a PbO₂ electrode in acetone/water mixed solvents that the current density at the same anode potential not only increases remarkably, but also the selectivity and the current efficiency of electrooxidation from 3\|picoline to nicotinic acid increase obviously compared with the pure water as the solvent. Electrooxidation conditions of 3-picoline in acetone/water mixed solvents was studied, and the selectivity and the current efficiency under various conditions were compared.

Key words: 3-Picoline, Acetone, Nicotinic acid, Electrooxidation

CLC Number:

O646

TrendMD:

XU Yu-Ling, CAO Xue-Jing, ZHANG Heng-Bin, ZHANG Yu-Min, LI Ke-Chang. Electrooxidation of 3-Picoline in Acetone/Water Mixed Solvents[J]. Chem. J. Chinese Universities, doi: .

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Electrooxidation of 3-Picoline in Acetone/Water Mixed Solvents

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