Synthesis and Properties of Styrene/Maleimide Copolymer with Active Side-group

Abstract

Abstract: Styrene/N-(4-hydroxyphenyl) maleimide copolymer(SHMI), which has an active side-group and can be reacted with other organic molecules with special optical and electrical properties, were synthesized. SHMI can be used as backbone for functional and special polymers. The structures of SHMI products were studied by FTIR, NMR and GPC. DSC and TGA were employed to study the thermal transition and thermal degradation of SHMI. It is shown that SHMI is an alternating copolymer with high glass transition temperature(T_g =526 K), good solubility and film-forming properties. The thermal degradation kinetics of SHMI can be fitted by Arrhenius equation. The initial thermal degradation temperature(T_d1) of SHMI is 661 K.

Key words: N-(4-Hydroxyphenyl) maleimide, Styrene/maleimide copolymer, Active side-group, Thermal stability

CLC Number:

TrendMD:

PU Hong-Ting, JIANG Wei-Chun, LIU Ling. Synthesis and Properties of Styrene/Maleimide Copolymer with Active Side-group[J]. Chem. J. Chinese Universities, 2005, 26(9): 1739.

[1]	CHANG Sihui, CHEN Tao, ZHAO Liming, QIU Yongjun. Thermal Degradation Mechanism of Bio-based Polybutylactam Plasticized by Ionic Liquids [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220353.
[2]	ZHANG Jun, WANG Bin, PAN Li, MA Zhe, LI Yuesheng. Synthesis and Properties of Imidazolium-based Polyethylene Ionomer [J]. Chem. J. Chinese Universities, 2020, 41(9): 2070.
[3]	RAN Shiya,SHEN Haifeng,LI Xiaonan,WANG Zilu,GUO Zhenghong,FANG Zhengping. Effect and Mechanism of Rare Earth Trifluoromethanesulfonate on the Thermal Stability of Polypropylene^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1333.
[4]	FANG Xijie,LIU Ruiyun,LIN Sen,SHI Lei,WANG Runwei,LI Yi,LI Junying. Synthesis of STW-zeotype Germanosilicate via Steam-assisted Crystallization^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 867.
[5]	YIN Mengxin,LIU Dongsheng,ZHAO Dongyue,DING Tong,TIAN Ye,LI Xingang. Effect of Copper Doping on Lean NO_x Trap Performance of Pt/Ba/Cu_xMg_1-_xAl₂O₄ Catalysts at High Temperatures ^† [J]. Chem. J. Chinese Universities, 2019, 40(10): 2170.
[6]	LIU Yi, XU Xiaozhou, MO Song, ZHAI Lei, HE Minhui, FAN Lin. Thermal Stability of Polyimide Resins Containing Siloxane Structure and Their High Temperature Structural Evolution [J]. Chem. J. Chinese Universities, 2019, 40(1): 187.
[7]	MENG Jiafeng, NI Xufeng, ZHENG Hao, SHEN Zhiquan. Copolymerization of Norbornene and 1-Octene Catalyzed by Bis(phenoxy-imine) Titanium Complex^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1853.
[8]	DU Shanshan, LI Yang, GUO Lei, LI Pengyu, CHAI Zhilong, WANG Tao, QUAN Dongqin, HE Junlin. Modification of Aptamer TBA with Extra Functional Groups and the Biological Activities^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2445.
[9]	LI Yang, LI Zhiwen, ZHU Junfei, LIU Shihui, HE Junlin. Construction of Pyrenyl Pairs in dsDNA: Fluorescent Properties of Multiple Pyrenyl-attached dsDNAs Through 7-Substituted 8-Aza-7-deaza-2'-deoxyadenosine Analogues^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2206.
[10]	LI Caixin, LIANG Xiaorong, GU Ju. Preparation and Characterization of Bagasse Nanocellulose^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1286.
[11]	LI Wei, WU Suhua, Ren Xinxin. Effect of Co-stabilizers on the Properties of Ba/Zn System [J]. Chem. J. Chinese Universities, 2017, 38(11): 2089.
[12]	LIU Yaoyao, DING Tong, ZHAO Dongyue, GAO Zhongnan, GUO Lihong, TIAN Ye, LI Xingang. Effect of Potassium Loading on the NO_x Storage and Reduction Performance of the CuO/K₂CO₃/MgAl₂O₄Catalyst at High Temperature^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 2006.
[13]	LIU Yaohua, LIN Yu, ZHANG Dongge, CHEN Chunlei, WU Guozhang, ZHANG Yan, LUAN Weiling. Fabrication of Natural Rubber/Chemically Reduced Graphene Oxide Nanocomposites and Nuclear Radiation Resistant Behavior^† [J]. Chem. J. Chinese Universities, 2016, 37(7): 1402.
[14]	LIU Jingwei, GUO Zhaoxia, YU Jian. Influence of Acrylonitrile-styrene Copolymer on the Thermal Stability of Polyoxymethylene Resin [J]. Chem. J. Chinese Universities, 2015, 36(9): 1853.
[15]	WANG Bin, LUO Haiyan, ZHANG Yonghong, SUN Yadong, LIU Chenjiang. Synthesis and Properties of Chiral Ionic Liquid Based on (R)-Thiazolidine-2-thione-4-carboxylate^† [J]. Chem. J. Chinese Universities, 2015, 36(8): 1530.

Synthesis and Properties of Styrene/Maleimide Copolymer with Active Side-group

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments