Synthesis and Selective Binding for Metal Ion of Double-armed Benzo-15-crown-5

Abstract

Abstract: Two new double-armed benzo-15-crown-5(2 and 3) were synthesized by reaction of 4,5-bis-(bromomethyl)-benzo-15-crown-5 with 2-naphthol and 2-mercaptobenzothiazole, respectively, and characterized by elemental analysis, mass, IR, ¹H NMR spectroscopies and X-ray diffraction, respectively. The crystal structure of compound 2 was reported as follows: Crown ether 2 crystallizes in the monoclinic system, space group P2₁ with cell parameters: a=1.262 2(9) nm, b=1.224 7(9) nm, c=2.016 0(16) nm, β=101.270(15)°. There is an intermolecular π^*

Key words: Double-armed crown ether, Cation slectivity, Crystal structure, Extraction

CLC Number:

O612

TrendMD:

HAN Jian-Rong, ZHANG Heng-Yi, LIU Yu. Synthesis and Selective Binding for Metal Ion of Double-armed Benzo-15-crown-5[J]. Chem. J. Chinese Universities, 2005, 26(7): 1273.

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Synthesis and Selective Binding for Metal Ion of Double-armed Benzo-15-crown-5

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