Synthesis, Structure and Nonlinear Optical Properties of Two-photon Photopolymerization Initiator BVPDA

Abstract

Abstract: A new two-photon photopolymerization initiator {4-[2-(4-bromophenyl)vinyl]phenyl}-diphenyl-amine(BVPDA) was synthesized and characterized by ¹H NMR, ¹³C NMR and elemental analyses. The crystal structure was characterized by X-ray diffraction structural analyses. BVPDA belongs to the triclinic space group P1 with a=1.083 4(3) nm, b=1.562 5(2) nm, c=1.964 0(2) nm, α=92.807(8)°, β=103.647(10)°, γ=106.676(13)°, V=3.070 5(10) nm³, Z=6, T=293(2) K, D_c=1.383 g/cm³, R₁=0.073 5 and wR=0.106 3. The linear absorption, one-photon fluorescence, one-photon fluorescence lifetime and two-photon fluorescence are experimentally studied. When pumped with 760 nm laser irradiation, BVPDA indicates a strong two-photon induced fluorescence of 462 nm. A microstructure using BVPDA as the initiator was fabricated using BVPDA as the initiator under irradiation of 200 fs, 76 MHz Ti:sapphire femtosecond laser at 760 nm.

Key words: Two-photon photopolymerization initator(BVPDA), Crystal structure, Nonlinear optical property, Microfabrication

CLC Number:

O621

TrendMD:

YAN Yun-Xing, TAO Xu-Tang, XU Gui-Bao, YU Wen-Tao, YANG Jia-Xiang, WU Yong-Zhong, YU Xiao-Qiang, ZHAO Xian, JIANG Min-Hua . Synthesis, Structure and Nonlinear Optical Properties of Two-photon Photopolymerization Initiator BVPDA[J]. Chem. J. Chinese Universities, 2005, 26(3): 562.

References

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