Self-assembly and Luminescence Property of Met allodendritic Supramolecule Consisting of a Functional Cryptand Core and Six Digold(Ⅰ) Branches

Chem. J. Chinese Universities ›› 2005, Vol. 26 ›› Issue (2): 376.

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Self-assembly and Luminescence Property of Met allodendritic Supramolecule Consisting of a Functional Cryptand Core and Six Digold(Ⅰ) Branches

YU Shu-Yan^1,3, ZHANG Zhong-Xing^1,2, LI Hui^1,2,4, HUANG Hai-Ping^1,2, ZHANG Rong-Ben¹, ZHANG Jian-Ping¹, CUI Yu-Xin⁵

1. State Key Laboratory of Polymer Physics and Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;
2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China;
3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
4. School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China;
5. Medical and Healthy Analysis Center, Peking University, Beijing 100083, China

Received:2004-10-27 Online:2005-02-10 Published:2005-02-10

Abstract

Abstract: Self-assembly of a functional cryptand core(1) having six dithiocarbamate groups and (dppm)Au₂Cl₂ in methanol followed by the addition of excess NH₄PF₆ affords a novel met allodendritic supramolecule(2). This dendritic supramolecule was characterized by NMR, MS, XPS, IR, UV-Vis, luminescence spectra and elemental analyses. The results show the concentration-dependent absorption and luminescent properties in acetonitrile solution for the title compound, which may be closely related to the intramolecular and intermolecular aggregation of digold(Ⅰ) branches through Au(Ⅰ)…Au(Ⅰ) interactions.

Key words: Self-assembly, Luminescence, Met allodendritic supramolecule, Cryptand

CLC Number:

O631

TrendMD:

YU Shu-Yan, ZHANG Zhong-Xing, LI Hui, HUANG Hai-Ping, ZHANG Rong-Ben, ZHANG Jian-Ping, CUI Yu-Xin. Self-assembly and Luminescence Property of Met allodendritic Supramolecule Consisting of a Functional Cryptand Core and Six Digold(Ⅰ) Branches[J]. Chem. J. Chinese Universities, 2005, 26(2): 376.

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Self-assembly and Luminescence Property of Met allodendritic Supramolecule Consisting of a Functional Cryptand Core and Six Digold(Ⅰ) Branches

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