Spectral Study of 5,10,15,20-Tetra(p-Chlorophenyl) PorphyrinLanthanide Complexes

Abstract

Abstract: The UV-Vis spectra, Infrared spectra and resonance Raman spectra of tetra(para-chlorophenyl)porphyrin and its coordination compounds LnT(%p%-Cl)PPOH(Ln; Tb, Lu, Er, Gd) were measured and investigated respectively. In UV-Vis spectra the effect of rare earth ions were discussed. Metal sensitive bands in IR spectra were found, and the effect of metal ion size on the marker bands frequencies in resonance Raman spectra was also discussed.

Key words: Porphyrin, UV-Vis spectra, Infrared spectra, Resonance Raman spectra

CLC Number:

O641

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JIA Hui-Ying, XU Wei-Qing, QI Ming-Hui, LIU Guo-Fa, LI Xiao-Ling, ZHAO Bing. Spectral Study of 5,10,15,20-Tetra(p-Chlorophenyl) PorphyrinLanthanide Complexes[J]. Chem. J. Chinese Universities, 2004, 25(2): 338.

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Spectral Study of 5,10,15,20-Tetra(p-Chlorophenyl) PorphyrinLanthanide Complexes

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