Theoretical Studies on Interaction Between the Calix[4]pyrrole and Anion Complex Systems--Density Functional Theory on the Calix[4]pyrrole-halide Anion Complex System

Chem. J. Chinese Universities ›› 2004, Vol. 25 ›› Issue (12): 2290.

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Theoretical Studies on Interaction Between the Calix[4]pyrrole and Anion Complex Systems--Density Functional Theory on the Calix[4]pyrrole-halide Anion Complex System

CHEN Pei-Quan^1,3, SUN Hong-Wei^1,3, CHEN Lan¹, SHEN Rong-Xin¹, YUAN Man-Xue¹, LAI Cheng-Ming^1,2

1. Department of Chemistry, Nankai University, Tianjin 300071, China;
2. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China;
3. Institute of Scientific Computing, Nankai University, Tianjin 300071, China

Received:2003-09-28 Online:2004-12-24 Published:2004-12-24

Abstract

Abstract: The density functional theory B3LYP/LANL2DZ methods were performed on the lowest energy conformation of free calix[4]pyrrole and the calix[4]pyrrole-halide anion complexes. The calculated results indicated that the interaction between calix[4]pyrrole and halide anions mainly involved hydrogen bonds interaction. The calculated results also implied the regular changes in molecular geometry features, in the differences of charge transfer, of frontier orbital energies, and of bonding, and in the thermochemistry parameters in recognition. These induced that the interaction between calix[4]pyrrole and halide anions decreased along the halide elemental period.

Key words: Calix[4]pyrrole, Halide anion, Interaction, Hydrogen bond

CLC Number:

O641

TrendMD:

CHEN Pei-Quan, SUN Hong-Wei, CHEN Lan, SHEN Rong-Xin, YUAN Man-Xue, LAI Cheng-Ming, . Theoretical Studies on Interaction Between the Calix[4]pyrrole and Anion Complex Systems--Density Functional Theory on the Calix[4]pyrrole-halide Anion Complex System[J]. Chem. J. Chinese Universities, 2004, 25(12): 2290.

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Theoretical Studies on Interaction Between the Calix[4]pyrrole and Anion Complex Systems--Density Functional Theory on the Calix[4]pyrrole-halide Anion Complex System

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