Hydrothermal Syntheses, Crystal Structures and Magnetic Properties of Na[M(nta)]·H2O(M=Co, Ni; nta=nitrilotriacetate)

Abstract

Abstract: Two new three-dimensional coordination polymers, Na [M(nta)]·H₂O(M=Co, Ni) were hydrothermally synthesized and their structures were solved by single-crystal X-ray diffraction.Their structures were analogous and the two crystals belong to the orthorhombic system with space group P2₁, and cell parameters a=0.7857(9) nm, b=0.9743(12) nm, c= 1.2190(18) nm, V=0.9334(2) nm³, Z=4 for Na [Co(nta)]·H₂O and a=0.7967(16) nm, b= 0.9752(2) nm, c=1.2182(2) nm, V=0.9465(3) nm³, Z=4 for Na [Ni(nta)]·H₂O.The structures of the title compounds are considered to be four M(nta)-octahedra connected by the sodiuMAtoms, thus the three-dimensional tunnels were formed.Variable temperature magnetic susceptibility indicates that the antiferromagnetic interaction existSIn Na[Co(nta)]·H₂O and Na [Ni(nta)]·H₂O.

Key words: Hydrothermal synthesis, Crystal structure, Coordination polymer, Magnetic properties

CLC Number:

O614

TrendMD:

DAI Zhi-Min, SHI Zhan, LI Guang-Hua, FU Wen-Sheng, XU Wei, FENG Shou-Hua. Hydrothermal Syntheses, Crystal Structures and Magnetic Properties of Na[M(nta)]·H₂O(M=Co, Ni; nta=nitrilotriacetate)[J]. Chem. J. Chinese Universities, 2003, 24(11): 1950.

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Hydrothermal Syntheses, Crystal Structures and Magnetic Properties of Na[M(nta)]·H₂O(M=Co, Ni; nta=nitrilotriacetate)

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