Syntheses and Characterization of Novel Open-framework Zinc Germanate Phosphates

Abstract

Abstract: Three open-framework zinc germanophosphates have been synthesized from ethylene glycol systems of Zn(Ac)₂·2H₂O-H₃PO₄-R-GeO₂-Py-EG, where R stands for an amine and EGfor ethylene glycol. It was found that by selecting proper amines as structure-directing templates during crystallization open-framework zinc germanophosphates were synthesized. The structures of the zinc germanophosphates were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), inductively coupled plasma(ICP) analysis, infrared spectroscopy(IR).

Key words: Solvothermal synthesis, Open-framework, Zinc germanate phosphate, Crystal

CLC Number:

O614

TrendMD:

LI Dong-Sheng, ZHU Guang-Shan, LI Ya-Feng, GAO Fei-Fei, LI Bin-Song, QIU Shi-Lun  . Syntheses and Characterization of Novel Open-framework Zinc Germanate Phosphates[J]. Chem. J. Chinese Universities, 2002, 23(9): 1673.

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Syntheses and Characterization of Novel Open-framework Zinc Germanate Phosphates

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