Preparation Mechanism and Application of Alcohol⁃modified Fe3O4 Magnetic Nanoparticles

doi:10.7503/cjcu20210077

Abstract

Abstract:

Herein， modified Fe₃O₄ particles（named as E-Fe₃O₄， P-Fe₃O₄ and D-Fe₃O₄， respectively） were prepared by chemical precipitation method using ethyleneglycol（EG）， polyethylene glycol（PEG） and mannitoll（D-M） as the separated modifier. The results showed that the alcohol molecules can be successfully modified on the surface of Fe₃O₄ particles， and the morphology， size， crystal phase and magnetic properties of Fe₃O₄ particles are not significantly affected. Modification mechanisms of Fe₃O₄ samples are studied by Fourier transform infrared spectroscopy， ion selective electrode method， Zeta potential and water contact angle tests. It is shown that the modification mechanism of P-Fe₃O₄ and D-Fe₃O₄ samples are associated with the hydrogen bonding of water molecules mediated， while more stable hydrogen bond can be formed between ethylene glycol and hydroxyl group on the surface of E-Fe₃O₄. Consequently， ethylene glycol was still fixed on the surface of Fe₃O₄ even under high temperature treatment（120 ℃）. E-Fe₃O₄ with hydrophobic group on the surface exhibits optimal hydrophilicity（contact angle was 32.92°） and water dispersion behavior（diameter was about 200―300 nm）. E-Fe₃O₄ with negative surface charge can be applied to remove cationic dye crystal violet（CV） from water and adsorption capacity was 19.33 mg/g， which was 2.3 times of that pristine Fe₃O₄（8.41 mg/g）. Besides， the addition of isopropanol is beneficial for CV desorption. This study not only provides a new method for preparing magnetic nano-Fe₃O₄ adsorption material， but also provides a theoretical basis for its application in the separation and adsorption of dye wastewater.

Key words: Fe₃O₄, Alcohol modification, Dispersion behavior, Remove, Crystal violet

CLC Number:

O647

TrendMD:

XU Yan, YANG Hongguo, NIU Huibin, TIAN Hailin, PIAO Hongguang, HUANG Yingping, FANG Yanfen. Preparation Mechanism and Application of Alcohol⁃modified Fe₃O₄ Magnetic Nanoparticles[J]. Chem. J. Chinese Universities, 2021, 42(8): 2564.

Figures/Tables 11

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c₀/(mg·L^-1)	q_e，exp/（mg·g^-1）	Pseudo?first?order rate equation			Pseudo?second?order rate equation
c₀/(mg·L^-1)	q_e，exp/（mg·g^-1）	q_e，cal/（mg·g^-1）	k₁/h^-1	R²	q_e，cal/（mg·g^-1）	k₂/（g·mmol^-1·h^-1）	R²
30	19.33	6.17	0.08826	0.7385	25.04	0.0444	0.9978

c₀/(mg·L^-1)	q_e，exp/（mg·g^-1）	Pseudo?first?order rate equation			Pseudo?second?order rate equation
c₀/(mg·L^-1)	q_e，exp/（mg·g^-1）	q_e，cal/（mg·g^-1）	k₁/h^-1	R²	q_e，cal/（mg·g^-1）	k₂/（g·mmol^-1·h^-1）	R²
30	19.33	6.17	0.08826	0.7385	25.04	0.0444	0.9978

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Preparation Mechanism and Application of Alcohol⁃modified Fe₃O₄ Magnetic Nanoparticles

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