Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (7): 1383.

• Articles • Previous Articles     Next Articles

Preparation of Polymer Electrolyte for Lithium-ion Battery

REN Xu-Mei1, GU Hui2, CHEN Li-Quan2, WU Feng1, HUANG Xue-Jie2   

  1. 1. School of Chemical Engineering and Materials Science, Beijing Institute of Technology, Beijing 100081, China;
    2. Laboratory for Solid State Ionics, Institute of Physics, Chinese Academy of Sciences, Beijing 100080, China
  • Received:2000-05-19 Online:2002-07-24 Published:2002-07-24

Abstract: With the final goal of developing lithium ion batteries having a plastic configuration, we have characterized a high conducting microporous PVDFplastic electrolyte for lithium ion batteries prepared by using the phase inversion process. Gel polymer electrolyte composed of PVDF-based microporous membrane, LiPF6-EC/DECshow a high ionic conductivity (above 10-3S/cm at room temperature), and good mechanical properties(102 kg/cm2). The half cells consisting of Li/GPE/MCMBshow excellent cycling characteristics and the stable discharge capacity is 306 mA·h/g. At a current density of 1.0 mA·h/cm2(0.5 C), the cell was shown to retain 79% of initial capacity after 100 cycles.

Key words: Lithium ion battery, Polymer electrolyte, PVDF, Phase inverse

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