Chem. J. Chinese Universities ›› 2019, Vol. 40 ›› Issue (11): 2332.doi: 10.7503/cjcu20190309

• Physical Chemistry • Previous Articles     Next Articles

Application of Polyethylene Separator Modified by Methyl Acrylic Polymer in Lithium Ion Battery

WU Wei1,LIU Yuchun1,ZHU Guancun1,AN Jiayu1,DOU Guangpeng1,WANG Yuyan1,LIU Jing1,*(),SUN Donglan2,*(),GUO Yeping3   

  1. 1. College of Chemical Engineering and Material Science, Tianjin 300457, China
    2. College of Science, Tianjin University of Science and Technology, Tianjin 300457, China
    3. Hangzhou Future Power Technology Co., Ltd., Hangzhou 311400, China
  • Received:2019-05-30 Online:2019-11-10 Published:2019-08-20
  • Contact: LIU Jing,SUN Donglan E-mail:jingliu@tust.edu.cn;sundonglan@tust.edu.cn
  • Supported by:
    ? Supported by the National Natural Science Foundation of China(21373150);The National Basic Research Program of China(2016IM030400)

Abstract:

Cyclic carbonate group was introduced into the side-chain of polymethyl methacrylate(PMMA) to prepare poly(2-oxo-1,3-dioxolan-4-yl) methyl methacrylate(PDOMMA), which was then coated on polyethylene separator of lithium ion battery. The thermal stability of PDOMMA and the effect of modification on wettability and electrolyte uptake ability of separator were studied by thermogravimetry(TG), differential scanning calorimetry(DSC), static contact angle test and electrolyte uptake rate test. Moreover, the effect of the modified separator on the performance of lithium ion battery was studied by galvanostatic charge and discharge test, alternating current(AC) impedance test, rate capability test and scanning electron microscopy(SEM). The results show that compared to the unmodified separator, the modified separator has an improved wettability with the electrolyte(the complete wetting is reached by 20 s), a higher uptake rate of electrolyte(440%), and better cycle performance of the related battery(discharge specific capacity increased by 12.3%).

Key words: Methyl acrylic polymer, Lithium ion battery, Polyethylene separator, Wettability

CLC Number: 

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