Hydrothermal Synthesis and Crystal Structure of a Three-dimensionalOpen-framework Compound, {[Cu(1,2-pn)-2]4[V18O42(H2O)]}n·8nH2O

Abstract

Abstract: The hydrothermal reaction of V₂O₅, Cu(CH₃COO)₂·H₂O, TMAOH and 1,2-diaminopropane gave a novel three-dimensional framework material, {[Cu(1,2-pn)₂]₄[V₁₈O₄₂(H₂O)]}_n ·8nH₂O, which was constructed from the mixed-valence {V₁₈O₄₂(H₂O)} clusters interconnected through {Cu(1,2-pn)₂} complex groups.{[Cu(1,2-pn)₂]₄[V₁₈O₄₂(H₂O)]}_n ·8nH₂O was characterized by IR, TGA and single-crystal X-ray diffraction.It crystallizes in tetragonal space group P4/nnc with a=1.5107(2) nm, c = 1.8645(4) nm, D_c = 2.028 g/cm³, Z = 2, R₁= 0.0631, wR₂ = 0.1538.

Key words: Polyoxovanadate, Crystal structure, Hydrothermal synthesis

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LIN Bi-Zhou, LIU Shi-Xiong. Hydrothermal Synthesis and Crystal Structure of a Three-dimensionalOpen-framework Compound, {[Cu(1,2-pn)-2]₄[V₁₈O₄₂(H₂O)]}_n·8nH₂O[J]. Chem. J. Chinese Universities, 2002, 23(4): 535.

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Hydrothermal Synthesis and Crystal Structure of a Three-dimensionalOpen-framework Compound, {[Cu(1,2-pn)-2]₄[V₁₈O₄₂(H₂O)]}_n·8nH₂O

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