Crystal Structure of Tri(8-quinolinol) Nickel Coordination Compound [Ni2(HQ)3Q3] ClO4

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (1): 22.

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Crystal Structure of Tri(8-quinolinol) Nickel Coordination Compound [Ni₂(HQ)₃Q₃] ClO₄

ZHANG Ming-Jie², HUANG Yan-Yi¹, HUANG Chun-Hui¹, XU Guang-Xian¹

1. State Key Laboratory of Rare Earth Materials Chemistryand Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
2. Departmentof Chemistry, Tianjin University, Tianjin 300072, China

Received:2001-01-08 Online:2002-01-24 Published:2002-01-24

Abstract

Abstract: A tri(8-quinolinol)nickel coordination compound, [Ni₂(HQ)₃Q₃] ClO₄, was synthesized and its crystal structure was determined by X-ray diffraction. The crystal structure indicated a space group of P2₁/c with a =1.6138(1) nm, b =1.5900(1) nm, c =1.9399(1) nm, β =94.663(2)°, V = 4.9612(6) nm³ and Z =4. Three strong hydrogen bonds were found in each unique unit between two tri(8-quinolinol) nickel fragments.

Key words: 8-Quinolinol, Nickel, Coordination compound, Crystal structure

CLC Number:

O614

TrendMD:

ZHANG Ming-Jie, HUANG Yan-Yi, HUANG Chun-Hui, XU Guang-Xian. Crystal Structure of Tri(8-quinolinol) Nickel Coordination Compound [Ni₂(HQ)₃Q₃] ClO₄[J]. Chem. J. Chinese Universities, 2002, 23(1): 22.

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Crystal Structure of Tri(8-quinolinol) Nickel Coordination Compound [Ni₂(HQ)₃Q₃] ClO₄

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