Preparation of Ni2P/N, S co-Doped Reduced Graphene Oxide Composites and Their Electrocatalytic Properties for Hydrogen Evolution†

doi:10.7503/cjcu20200161

Abstract

Abstract:

Developing new type of electrolyzed water catalysts is very important. In this work, nickel phosphide nanocrystals supported on N, S co-doped reduced graphene oxide(Ni₂P/NSRGO) as a high activity catalyst was synthesized by the simple hydrothermal process. The graphene can anchor nickel phosphide and improve catalytic performance. The results of electrochemical test showed that the Ni₂P/NSRGO composite electrocatalyst showed better hydrogen evolution performance than Ni₂P/NRGO and Ni₂P/RGO catalysts, indicating the addition of N and S has a positive effect on the improvement of hydrogen evolution performance. The Ni₂P/NSRGO nanocrystals catalyst shows excellent performance with a small Tafel slope of 35 mV/dec, longterm durability and a low overpotential(η₁₀=140 mV) in 0.5 mol/L H₂SO₄ for the hydrogen evolution reaction(HER).

Key words: Hydrogen evolution reaction, Electrocatalyst, Nickel phosphide nanocrystal, Nitrogen-sulfur double-doping

CLC Number:

O646
O613.6

TrendMD:

ZHAO Guoqing, YUAN Zhao, WANG Lian, GUO Zhuo. Preparation of Ni₂P/N, S co-Doped Reduced Graphene Oxide Composites and Their Electrocatalytic Properties for Hydrogen Evolution^†[J]. Chem. J. Chinese Universities, 2020, 41(7): 1575.

Figures/Tables 8

References 31

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Preparation of Ni₂P/N, S co-Doped Reduced Graphene Oxide Composites and Their Electrocatalytic Properties for Hydrogen Evolution^†

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Catalyst	Electrolyte	η₁₀/mV	Tafels lope/(mV·dec^-1)	Ref.
Ni₂P@C/G	0.5 mol/L H₂SO₄	285	44	[23]
Ni2P/NRGO	0.5 mol/L H₂SO₄	80	93.1	[24]
Ni₂P/NPPC	0.5 mol/L H₂SO₄	159	74	[25]
Ni₂P/CC	0.5 mol/L H₂SO₄	119	50	[26]
Ni₂P/C	0.5 mol/L H₂SO₄	94	113.2	[27]
NFP@NG	0.5 mol/L H₂SO₄	250	91	[28]
Ni₂P/Ni	0.5 mol/L H₂SO₄	140	68	[29]
Ni₂P@C-400	0.5 mol/L H₂SO₄	186	85	[30]
Ni₂P/NSRGO-2	0.5 mol/L H₂SO₄	140	35	This work

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