Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (7): 1169.

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Studies on 12-Tungstophosphoric Heteropolyacid Supported SBA-15 Catalysts

ZHANG Xue-Zheng, YUE Ying-Hong, GAO Zi   

  1. Department of Chemistry, Fudan University, Shanghai 200433, China
  • Received:2000-06-30 Online:2001-07-24 Published:2001-07-24

Abstract: Aseries of SBA-15 supported H3PW12O40 (PW) catalysts were prepared and characterized. PWcrystal phase was not observed in XRDpatterns at PWloading as high as 60%. PWdispersed on the supports retains its Keggin structure, but a strong chemical interaction between PWand SBA-15 supports is present. The activity of the catalysts can be adjusted by varying PWloading. PW/SBA-15 catalysts are promising mesoporous solid acid catalysts for medium strong and weak acid catalyzed reactions.

Key words: SBA-15 molecular sieve, 12 Tungstophosphoric acid, Acidity, Catalytic activity

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