Preparation and Catalytic Activity of Graphene Supported Pt/Co Nanoparticles for Hydrogen Generation from KBH4

doi:10.7503/cjcu20190165

Abstract

Abstract: Graphene supported Pt/Co bimetallic nanoparticles(GBNPS) were prepared using a chemical co-reduction method. The obtained GBNPS were characterized by transmission electron microscope(TEM), high-resolution transmission electron microscopy(HRTEM), X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS). The effects of metal compositions on the hydrolysis reaction of the alkaline KBH₄ solution were studied. The results indicated that the average particle size of GBNPS was from 3.2 nm to 3.9 nm. Pt₂₀Co₈₀ GBNPS displayed the highest catalytic activity, showing a high hydrogen release rate of 35973.35 mol_H₂·h^-1·mol^-1_Pt at 35℃. Pt₂₀Co₈₀ GBNPS showed the corresponding apparent activation energy of 36 kJ/mol for the hydrolysis of an alkaline KBH₄.

Key words: Graphene supported, Pt/Co bimetallic nanoparticles, KBH₄, Catalytic activity

CLC Number:

O643

TrendMD:

LI Xiaoli, HUANG Liang, DUAN Hongjuan, ZHANG Li, ZHANG Haijun. Preparation and Catalytic Activity of Graphene Supported Pt/Co Nanoparticles for Hydrogen Generation from KBH₄[J]. Chem. J. Chinese Universities, 2019, 40(8): 1662.

References 33

[1]	Marrero-AIfonso Y. E., Beaird M. A., Davis A. T., Ind. Eng. Chem. Res., 2009, 48(8), 3703-3712
[2]	Wang L., Sun Y. X., Miao Y. L., Sun H., Chem. J. Chinese Universities, 2011, 32(3), 758-764(王琳, 孙迎新, 苗延霖, 孙淮. 高等学校化学学报, 2011, 32(3), 758-764)
[3]	Liu H., Xu F., Sun L. X., Cao Z., Zhou H. Y., Chem. J. Chinese Universities, 2013, 34(8), 1953-1958(刘昊, 徐芬, 孙立贤, 曹忠, 周怀营. 高等学校化学学报, 2013, 34(8), 1953-1958)
[4]	Jiang H. L., Singh S. K., Yan J. M., Zhang X. B., Xu Q., ChemSusChem, 2010, 3(5), 541-549
[5]	Xu Q., Yadav M., Energy & Environmental Science, 2012, 5(12), 9698-9725
[6]	Brown H. C., Brown C. A., J. Am. Chem. Soc., 1962, 84(8), 1493-1494
[7]	Schlesinger H. I., Brown H. C., Finholt A. E., Gilbreath J. R., Hoekstra H. R., Hyde E. K., J. Am. Chem. Soc., 1953, 75(1), 215-219
[8]	Li Z. P., Chen L. L., Liu B. H., J. Power Sources, 2008, 180(1), 530-534
[9]	Liu C. H., Chen B. H., Hsueh C. L., Ku J. R., Int. J. Hydrogen Energy, 2009, 34(5), 2153-2163
[10]	Kong D. C., Gu Y. J., Xiang S., Wang P., Cheng J., Zhang H. J., Zhang S. W., Chem. J. Chinese Universities, 2013, 34(10), 2377-2382(孔德成, 古亚军, 向胜, 王鹏, 成君, 张海军, 张少伟. 高等学校化学学报, 2013, 34(10), 2377-2382)
[11]	Zhao W. G., Su L., Zhou Z. N., Zhang H. J., Lu L. L., Zhang S. W., Acta Phys.-Chim. Sin., 2015, 331(1), 210-218(赵万国, 苏丽, 周振宁, 张海军, 鲁礼林, 张少伟. 物理化学学报, 2015, 31(1), 210-218)
[12]	Wang L. Q., Jiao C. P., Li S. S., Huang Z. X., Zhao W. G., Zhang H. J., Chemietry, 2017, 80(3), 283-287(王丽琼, 焦成鹏, 李赛赛, 黄珍霞, 赵万国, 张海军. 化学通报, 2017, 80(3), 283-287)
[13]	Huang L., Jiao C. P., Wang L. Q., Huang Z. L., Liang F., Liu S. M., Wang Y. H., Zhang H. J., Zhang S. W., Nanotechnology, 2018, 29(4), 044002-1-9
[14]	Zhang H. J., Watanabe T., Okumura M., Haruta M., Toshima N., Nat. Mater., 2012, 11(1), 49-52
[15]	Zhang H. J., Okumura M., Toshima N., J. Phys. Chem. C, 2011, 115(30), 14883-14891
[16]	Zhang Z. L., Song H., Liu S. B., Li Y. B., Hao X. G., Duan D. H., Sun Y. P., Rare Metal Mat. Eng., 2012, 41(1), 58-63(张忠林, 宋慧, 刘世斌, 李一兵, 郝晓刚, 段东红, 孙彦平. 稀有金属材料与工程, 2012, 41(1), 58-63)
[17]	Qiao B. T., Wang A. Q., Yang X. F., Allard L. F., Jiang Z., Cui Y. T., Liu J. Y., Li J., Zhang T., Nat. Chem., 2011, 3(8), 634-641(乔波涛, 王爱琴, 杨小峰, Allard L. F., 姜政, 崔艺涛, 刘景月, 李隽, 张涛. 自然化学, 2011, 3(8), 634-641)
[18]	Xing J., Chen J. F., Li Y. H., Yuan W. T., Zhou Y., Zheng L. R., Wang H. F., Hu P., Wang Y., Zhao H. J., Wang Y., Yang H. G., Chem. Eur. J., 2014, 20(8), 2138-2144
[19]	Sun S. H., Zhang G. X., Gauquelin N., Chen N., Zhou J. G., Yang S. L., Chen W. F., Meng X. B., Geng D. S., Banis M. N., Li R. Y., Ye S. Y., Knights S. N., Botton G. A., Sham T. K., Sun X. L., Sci. Rep., 2013, 3(5), 65-65
[20]	Yan H., Cheng H., Yi H., Lin Y., Yao T., Wang C. L., Li J. J., Wei S. Q., Lu J. L., J. Am. Chem. Soc., 2015, 137(33), 10484-10487
[21]	Jiang H. L., Umegaki T., Akita T., Zhang X. B., Haruta M., Xu Q., Chem. Eur. J., 2010, 16(10), 3132-3137
[22]	Lu L. L., Shu H. F., Ruan Z. H., Ni J. Q., Zhang H. J., Chem. J. Chinese Universities, 2018, 39(5), 949-955(鲁礼林, 舒红飞, 阮祝华, 倪嘉琪, 张海军. 高等学校化学学报, 2018, 39(5), 949-955)
[23]	Priante F., Salim M., Ottaviano L., Perrozzi F., Nanotechnology, 2018, 29(7), 075704
[24]	Hellgren N., Haasch R. T., Schmidt S., Hultman L., Petrov I., Carbon, 2016, 108, 242-252
[25]	Bertóti I., Mohai M., László K., Carbon, 2015, 84, 185-196
[26]	Liu G. G., Ye H. Q., Li A. T., Zhu C. Y., Jiang H., Liu Y., Han K., Zhou Y. H., Carbon, 2016, 110, 56-61
[27]	Tan B. J., Klabunde K. J., Sherwood P. M. A., J. Am. Chem. Soc., 1991, 113(3), 855-861
[28]	Kim J. D., Choi M Y., Choi H. C., Appl. Surf. Sci., 2017, 420, 700-706
[29]	Xiang S., Gu Y. J., Wang P., Cheng J., Kong D. C., Zhang H. J., Zhang S. W., J. Process. Eng., 2014, 14(5), 874-879(向胜, 古亚军, 王鹏, 成君, 孔德成, 张海军, 张少伟. 过程工程学报, 2014, 14(5), 874-879)
[30]	Stamenkovic V. R., Bongjin S. M., Matthias A., Mayrhofer K. J. J., Lucas C. A., Wang G. F., Ross P. N., Markovic N. M., Nat. Mater., 2007, 6(3), 241-247
[31]	Dae-Wook K., Oi Lun L., Nagahiro S., Phys. Chem. Chem. Phys., 2015, 17(1), 407-247
[32]	Fang H., Wen M., Chen H. X., Wu Q. S., Li W. Y., Nanoscale, 2016, 8(1), 536-542
[33]	Zhang J. M., Chen G. Z., Guay D., Chaker M., Ma D. L., Nanoscale, 2014, 6(4), 2125-2130

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Preparation and Catalytic Activity of Graphene Supported Pt/Co Nanoparticles for Hydrogen Generation from KBH₄

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