PAMAM Dendritic Titanium Tetrachloride Complexes and Their Catalytic Reactivity

Abstract

Abstract: The modification of PAMAM( G=30) dendrimers was achieved by using aldehyde, benzyl chloride and trityl chloride as reaction agents, respectively. The complexes were synthesized simply by dropping TiCl₄ solution into the modified PAMAMdendrimers that were dissolved in certain solvent. The quantity of Ti contained in the complexes increased as the adding amount of TiCl₄ was increased. The polymerization of α methyl styrene catalyzed by the complexes was accomplished and it has shown that the complexes possessed catalytic function.

Key words: Dendrimer, Complex, Titanium tetrachloride, α-Methyl styrene

CLC Number:

O631

TrendMD:

WANG Jin-Feng, JIA Xin-Ru, JIN Zhong, ZHANG Wei-Cheng, FAN Yu, LI Ming-Qian, Wei-Yan . PAMAM Dendritic Titanium Tetrachloride Complexes and Their Catalytic Reactivity[J]. Chem. J. Chinese Universities, 2001, 22(4): 709.

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PAMAM Dendritic Titanium Tetrachloride Complexes and Their Catalytic Reactivity

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