Fluorescence Spectral Studies on the Coordination of Calix[4]arenes Bearing Boronic Acid Moieties with Amino Acids

Abstract

Abstract: Coordination of ten kinds of calix[4]arenes bearing boronic acid moieties with four kinds of amino acids was studied by using fluorescence spectrometry. The stability constants( K_s) of the complexes of calix[4]arenes bearing boronic acid moieties with amino acids and Gibbs free energy change(-Δ G °) of the coordination reactions were calculated according to the modified Hilderbrand Benesi equation. The results obtained indicated that the coordination abilities and selectivities of Lalanine with calix[4]arenes bearing boronic acid moieties were stronger than that of the other amino acids, and that the above calix[4]arene derivatives could be used for identification of D-alanine.

Key words: Calix[4]arene, Amino acids, Coordination, Fluorescence spectrometry

CLC Number:

O657

TrendMD:

LU Kui, WU Yang-Jie, LI Yong-Hong, SHI Ya-Lin, ZHOU Zhi-Xian . Fluorescence Spectral Studies on the Coordination of Calix[4]arenes Bearing Boronic Acid Moieties with Amino Acids[J]. Chem. J. Chinese Universities, 2001, 22(4): 581.

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Fluorescence Spectral Studies on the Coordination of Calix[4]arenes Bearing Boronic Acid Moieties with Amino Acids

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