Phase Equilibrium of the Ternary System La(ClO4)3-BAPOAP-H2O(30 ℃) and the Syntheses and Characterization of La2(BAPOAP)3(ClO4)6

Abstract

Abstract: The phase equilibrium of the ternary system La(ClO₄)₃BAPOAPH₂Oat 30 ℃ was studied by means of the isothermal solubility method. The incongruent compound, La₂(BAPOAP)₃(ClO₄)₆, was discovered. Based on the results of phase equilibrium, the series compounds Ln2(BAPOAP)₃(ClO₄)₆ were synthesized and characterized by chemical analyses, elemental analyses, IRspectra and TGDTGanalyses.

Key words: Lanthanide perchlorate, Lanthanum system, N,N'Bis(antipyrin-4-yl)oxamide, Ternary system, Solubility, Phase equilibrium

CLC Number:

O658.6

TrendMD:

TANG ZongXun, LIANG HongBin, CUI Bing . Phase Equilibrium of the Ternary System La(ClO₄)₃-BAPOAP-H₂O(30 ℃) and the Syntheses and Characterization of La₂(BAPOAP)₃(ClO₄)₆[J]. Chem. J. Chinese Universities, 2001, 22(12): 1990.

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Phase Equilibrium of the Ternary System La(ClO₄)₃-BAPOAP-H₂O(30 ℃) and the Syntheses and Characterization of La₂(BAPOAP)₃(ClO₄)₆

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