Synthesis of Tetra(4-n-decanoyloxyphenyl)porphyrin Complexes and Fourier Transform Infrared Photoacoustic Spectra

Abstract

Abstract: Six complexes of tetra(4-n-octanoyloxyphenyl)porphyins with Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) have been synthesized in mixed solvents CH₂Cl ²⁺DMF. The complexes were determined by elemental analysis, UV-Vis, FTIRphotoacoustic spectrum, ¹H NMRand molar conductivity measurement. The domains of stability and the structure of the liquid crystalline phases are determined by optical microscopy and differential scanning calorimerials(DSC). The fourier transform infrared photoacoustic spectra of TDPPH₂ and its complexes in the range of 3600—190 cm^-1 were measured and investigated.

Key words: Tetra(4-n-octanoyloxyphenyl)porphyrin, Complex, Porphyrin liquid crystal, Infrared photoacoustic spectra

CLC Number:

O614

TrendMD:

LIU Wei, SHI Tong-Shun, AN Qing-Da, YANG Da-Zhi . Synthesis of Tetra(4-n-decanoyloxyphenyl)porphyrin Complexes and Fourier Transform Infrared Photoacoustic Spectra[J]. Chem. J. Chinese Universities, 2001, 22(1): 16.

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Synthesis of Tetra(4-n-decanoyloxyphenyl)porphyrin Complexes and Fourier Transform Infrared Photoacoustic Spectra

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